Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)

In the title compound, [Mn(C(8)H(5)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Mn(II) atom is six-coordinated by two N and two O atoms from two 1H-benzimidazole-2-carboxyl­ate (L) ligands and by two O atoms from two ethanol mol­ecules in a distorted octa­hedral geometry. The mean planes of the two L ligands a...

Descripción completa

Detalles Bibliográficos
Autores principales: Nie, Jian-Hua, Lin, Yue-Hua, Xu, Chun-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470162/
https://www.ncbi.nlm.nih.gov/pubmed/23125606
http://dx.doi.org/10.1107/S1600536812039475
_version_ 1782246209308590080
author Nie, Jian-Hua
Lin, Yue-Hua
Xu, Chun-Tao
author_facet Nie, Jian-Hua
Lin, Yue-Hua
Xu, Chun-Tao
author_sort Nie, Jian-Hua
collection PubMed
description In the title compound, [Mn(C(8)H(5)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Mn(II) atom is six-coordinated by two N and two O atoms from two 1H-benzimidazole-2-carboxyl­ate (L) ligands and by two O atoms from two ethanol mol­ecules in a distorted octa­hedral geometry. The mean planes of the two L ligands are inclined to each other at 7.6 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the ab plane.
format Online
Article
Text
id pubmed-3470162
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34701622012-11-02 Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II) Nie, Jian-Hua Lin, Yue-Hua Xu, Chun-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mn(C(8)H(5)N(2)O(2))(2)(C(2)H(5)OH)(2)], the Mn(II) atom is six-coordinated by two N and two O atoms from two 1H-benzimidazole-2-carboxyl­ate (L) ligands and by two O atoms from two ethanol mol­ecules in a distorted octa­hedral geometry. The mean planes of the two L ligands are inclined to each other at 7.6 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the ab plane. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470162/ /pubmed/23125606 http://dx.doi.org/10.1107/S1600536812039475 Text en © Nie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nie, Jian-Hua
Lin, Yue-Hua
Xu, Chun-Tao
Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)
title Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)
title_full Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)
title_fullStr Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)
title_full_unstemmed Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)
title_short Bis(1H-benzimidazole-2-carboxyl­ato-κ(2) N (3),O)bis­(ethanol-κO)manganese(II)
title_sort bis(1h-benzimidazole-2-carboxyl­ato-κ(2) n (3),o)bis­(ethanol-κo)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470162/
https://www.ncbi.nlm.nih.gov/pubmed/23125606
http://dx.doi.org/10.1107/S1600536812039475
work_keys_str_mv AT niejianhua bis1hbenzimidazole2carboxylatok2n3obisethanolkomanganeseii
AT linyuehua bis1hbenzimidazole2carboxylatok2n3obisethanolkomanganeseii
AT xuchuntao bis1hbenzimidazole2carboxylatok2n3obisethanolkomanganeseii

Ejemplares similares