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Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]

In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The oth...

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Detalles Bibliográficos
Autor principal: Zhang, Yongmei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470163/
https://www.ncbi.nlm.nih.gov/pubmed/23125607
http://dx.doi.org/10.1107/S1600536812039669
Descripción
Sumario:In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The other Ag(I) ion, lying on an inversion center, is coordinated by two O atoms from two L ligands and two N atoms from two 1,4-bis­(imidazol-1-ylmeth­yl)benzene ligands in a distorted square-planar geometry. An additional Ag⋯Ag [3.0119 (3) Å] inter­action links the Ag(I) ions into a chain along [010]. The two types of ligands have mirror symmetry and connect the Ag(I) ions into a layer parallel to (100).