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Poly[[μ(2)-1,4-bis(imidazol-1-ylmethyl)benzene](μ(4)-3,5,9,11-tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diido)disilver(I)]
In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The oth...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470163/ https://www.ncbi.nlm.nih.gov/pubmed/23125607 http://dx.doi.org/10.1107/S1600536812039669 |
Sumario: | In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetraoxo-4,10-diazatetracyclo[5.5.2.0(2,6).0(8,12)]tetradec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The other Ag(I) ion, lying on an inversion center, is coordinated by two O atoms from two L ligands and two N atoms from two 1,4-bis(imidazol-1-ylmethyl)benzene ligands in a distorted square-planar geometry. An additional Ag⋯Ag [3.0119 (3) Å] interaction links the Ag(I) ions into a chain along [010]. The two types of ligands have mirror symmetry and connect the Ag(I) ions into a layer parallel to (100). |
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