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Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]

In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The oth...

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Autor principal: Zhang, Yongmei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470163/
https://www.ncbi.nlm.nih.gov/pubmed/23125607
http://dx.doi.org/10.1107/S1600536812039669
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author Zhang, Yongmei
author_facet Zhang, Yongmei
author_sort Zhang, Yongmei
collection PubMed
description In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The other Ag(I) ion, lying on an inversion center, is coordinated by two O atoms from two L ligands and two N atoms from two 1,4-bis­(imidazol-1-ylmeth­yl)benzene ligands in a distorted square-planar geometry. An additional Ag⋯Ag [3.0119 (3) Å] inter­action links the Ag(I) ions into a chain along [010]. The two types of ligands have mirror symmetry and connect the Ag(I) ions into a layer parallel to (100).
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spelling pubmed-34701632012-11-02 Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)] Zhang, Yongmei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(2)(C(12)H(8)N(2)O(4))(C(14)H(14)N(4))](n), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by two N atoms from two 3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diide (L) ligands in a nearly linear arrangement. The other Ag(I) ion, lying on an inversion center, is coordinated by two O atoms from two L ligands and two N atoms from two 1,4-bis­(imidazol-1-ylmeth­yl)benzene ligands in a distorted square-planar geometry. An additional Ag⋯Ag [3.0119 (3) Å] inter­action links the Ag(I) ions into a chain along [010]. The two types of ligands have mirror symmetry and connect the Ag(I) ions into a layer parallel to (100). International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470163/ /pubmed/23125607 http://dx.doi.org/10.1107/S1600536812039669 Text en © Yongmei Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yongmei
Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]
title Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]
title_full Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]
title_fullStr Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]
title_full_unstemmed Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]
title_short Poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(I)]
title_sort poly[[μ(2)-1,4-bis­(imidazol-1-ylmethyl)­benzene](μ(4)-3,5,9,11-tetra­oxo-4,10-diaza­tetra­cyclo­[5.5.2.0(2,6).0(8,12)]tetra­dec-13-ene-4,10-diido)disilver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470163/
https://www.ncbi.nlm.nih.gov/pubmed/23125607
http://dx.doi.org/10.1107/S1600536812039669
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