Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium

In the crystal structure of the title compound, [Ru(3)(C(9)H(11)P)H(2)(C(18)H(15)P)(CO)(8)], the triangular Ru(3) unit is capped with one mesitylphosphin­idene ligand. In the trigonal–pyramidal Ru(3)P core, one Ru(II) atom is coordinated by a triphenyl­phosphane ligand in a terminal fashion. Two hyd...

Descripción completa

Detalles Bibliográficos
Autor principal: Kakizawa, Taeko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470165/
https://www.ncbi.nlm.nih.gov/pubmed/23125609
http://dx.doi.org/10.1107/S1600536812039499
_version_ 1782246209998553088
author Kakizawa, Taeko
author_facet Kakizawa, Taeko
author_sort Kakizawa, Taeko
collection PubMed
description In the crystal structure of the title compound, [Ru(3)(C(9)H(11)P)H(2)(C(18)H(15)P)(CO)(8)], the triangular Ru(3) unit is capped with one mesitylphosphin­idene ligand. In the trigonal–pyramidal Ru(3)P core, one Ru(II) atom is coordinated by a triphenyl­phosphane ligand in a terminal fashion. Two hydride ligands bridge over two Ru—Ru bonds. These Ru—Ru bonds [2.9400 (4) and 2.9432 (4) Å] are slightly longer than the nonhydride-bridged Ru—Ru bond [2.8146 (4) Å]. The terminal triphenyl­phosphane ligand coordinates to the Ru(II) atom, which is involved in two hydride bridges.
format Online
Article
Text
id pubmed-3470165
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34701652012-11-02 Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium Kakizawa, Taeko Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ru(3)(C(9)H(11)P)H(2)(C(18)H(15)P)(CO)(8)], the triangular Ru(3) unit is capped with one mesitylphosphin­idene ligand. In the trigonal–pyramidal Ru(3)P core, one Ru(II) atom is coordinated by a triphenyl­phosphane ligand in a terminal fashion. Two hydride ligands bridge over two Ru—Ru bonds. These Ru—Ru bonds [2.9400 (4) and 2.9432 (4) Å] are slightly longer than the nonhydride-bridged Ru—Ru bond [2.8146 (4) Å]. The terminal triphenyl­phosphane ligand coordinates to the Ru(II) atom, which is involved in two hydride bridges. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470165/ /pubmed/23125609 http://dx.doi.org/10.1107/S1600536812039499 Text en © Taeko Kakizawa 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kakizawa, Taeko
Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium
title Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium
title_full Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium
title_fullStr Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium
title_full_unstemmed Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium
title_short Octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium
title_sort octa­carbonyldi-μ(2)-hydrido-[μ(3)-(1,3,5-trimethyl­phen­yl)phosphinidene](tri­phenyl­phosphane)-triangulo-triruthenium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470165/
https://www.ncbi.nlm.nih.gov/pubmed/23125609
http://dx.doi.org/10.1107/S1600536812039499
work_keys_str_mv AT kakizawataeko octacarbonyldim2hydridom3135trimethylphenylphosphinidenetriphenylphosphanetriangulotriruthenium

Ejemplares similares