Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)}

In the centrosymmetric binuclear molecule of the title complex, [Hg(2)Cl(4)(C(14)H(14)N(2))(2)], the five-coordinated Hg(II) ions have a distorted square-pyramidal geometry defined by two N atoms belonging to the chelating imino­pyridine ligand and three Cl atoms. The benzene and pyridine rings are...

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Autores principales: Hoseyni, Seyed Jalal, Talei Bavil Olyai, Mohamad Reza, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470166/
https://www.ncbi.nlm.nih.gov/pubmed/23125610
http://dx.doi.org/10.1107/S1600536812039050
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author Hoseyni, Seyed Jalal
Talei Bavil Olyai, Mohamad Reza
Notash, Behrouz
author_facet Hoseyni, Seyed Jalal
Talei Bavil Olyai, Mohamad Reza
Notash, Behrouz
author_sort Hoseyni, Seyed Jalal
collection PubMed
description In the centrosymmetric binuclear molecule of the title complex, [Hg(2)Cl(4)(C(14)H(14)N(2))(2)], the five-coordinated Hg(II) ions have a distorted square-pyramidal geometry defined by two N atoms belonging to the chelating imino­pyridine ligand and three Cl atoms. The benzene and pyridine rings are oriented at a dihedral angle of 56.7 (6)°. The crystal packing is stabilized by C—H⋯Cl hydrogen bonds and π–π inter­actions between the pyridine rings [centroid–centroid distance = 3.796 (6) Å].
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spelling pubmed-34701662012-11-02 Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)} Hoseyni, Seyed Jalal Talei Bavil Olyai, Mohamad Reza Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear molecule of the title complex, [Hg(2)Cl(4)(C(14)H(14)N(2))(2)], the five-coordinated Hg(II) ions have a distorted square-pyramidal geometry defined by two N atoms belonging to the chelating imino­pyridine ligand and three Cl atoms. The benzene and pyridine rings are oriented at a dihedral angle of 56.7 (6)°. The crystal packing is stabilized by C—H⋯Cl hydrogen bonds and π–π inter­actions between the pyridine rings [centroid–centroid distance = 3.796 (6) Å]. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470166/ /pubmed/23125610 http://dx.doi.org/10.1107/S1600536812039050 Text en © Hoseyni et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hoseyni, Seyed Jalal
Talei Bavil Olyai, Mohamad Reza
Notash, Behrouz
Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)}
title Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)}
title_full Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)}
title_fullStr Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)}
title_full_unstemmed Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)}
title_short Di-μ-chlorido-bis­{chlorido[2,3-dimethyl-N-(pyridin-2-yl­methyl­idene)aniline-κ(2) N,N′]mercury(II)}
title_sort di-μ-chlorido-bis­{chlorido[2,3-dimethyl-n-(pyridin-2-yl­methyl­idene)aniline-κ(2) n,n′]mercury(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470166/
https://www.ncbi.nlm.nih.gov/pubmed/23125610
http://dx.doi.org/10.1107/S1600536812039050
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AT notashbehrouz dimchloridobischlorido23dimethylnpyridin2ylmethylideneanilinek2nnmercuryii

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