Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis­(triphenyl­phosphane-κP)copper(I) methanol monosolvate

In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetra­hedral, defined by two P atoms of two triphenyl­phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol­...

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Detalles Bibliográficos
Autores principales: Jiang, Yu-Han, Qiu, Qi-Ming, Jiang, Rui-Xia, Huang, Xu, Jin, Qiong-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470167/
https://www.ncbi.nlm.nih.gov/pubmed/23125611
http://dx.doi.org/10.1107/S1600536812039165
Descripción
Sumario:In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetra­hedral, defined by two P atoms of two triphenyl­phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol­ecules and the methanol solvent mol­ecules are connected via N—H⋯O and O—H⋯I hydrogen bonds, forming a chain along [010]. An intra­molecular N—H⋯I hydrogen bond is also observed.

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