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Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate
In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetrahedral, defined by two P atoms of two triphenylphosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470167/ https://www.ncbi.nlm.nih.gov/pubmed/23125611 http://dx.doi.org/10.1107/S1600536812039165 |
| _version_ | 1782246210498723840 |
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| author | Jiang, Yu-Han Qiu, Qi-Ming Jiang, Rui-Xia Huang, Xu Jin, Qiong-Hua |
| author_facet | Jiang, Yu-Han Qiu, Qi-Ming Jiang, Rui-Xia Huang, Xu Jin, Qiong-Hua |
| author_sort | Jiang, Yu-Han |
| collection | PubMed |
| description | In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetrahedral, defined by two P atoms of two triphenylphosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex molecules and the methanol solvent molecules are connected via N—H⋯O and O—H⋯I hydrogen bonds, forming a chain along [010]. An intramolecular N—H⋯I hydrogen bond is also observed. |
| format | Online Article Text |
| id | pubmed-3470167 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34701672012-11-02 Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate Jiang, Yu-Han Qiu, Qi-Ming Jiang, Rui-Xia Huang, Xu Jin, Qiong-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuI(C(8)H(8)N(2)S)(C(18)H(15)P)(2)]·CH(3)OH, the coordination environment around the Cu(I) atom is distorted tetrahedral, defined by two P atoms of two triphenylphosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex molecules and the methanol solvent molecules are connected via N—H⋯O and O—H⋯I hydrogen bonds, forming a chain along [010]. An intramolecular N—H⋯I hydrogen bond is also observed. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470167/ /pubmed/23125611 http://dx.doi.org/10.1107/S1600536812039165 Text en © Jiang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jiang, Yu-Han Qiu, Qi-Ming Jiang, Rui-Xia Huang, Xu Jin, Qiong-Hua Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate |
| title | Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate |
| title_full | Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate |
| title_fullStr | Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate |
| title_full_unstemmed | Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate |
| title_short | Iodido[5-methyl-1H-benzimidazole-2(3H)-thione-κS]bis(triphenylphosphane-κP)copper(I) methanol monosolvate |
| title_sort | iodido[5-methyl-1h-benzimidazole-2(3h)-thione-κs]bis(triphenylphosphane-κp)copper(i) methanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470167/ https://www.ncbi.nlm.nih.gov/pubmed/23125611 http://dx.doi.org/10.1107/S1600536812039165 |
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