Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)]

The title complex, [Cu(2)(C(16)H(10)NO(2))(4)(CH(3)OH)(2)], consists of centrosymmetric wheel-shaped dinuclear neutral mol­ecules in which each Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by four O atoms of carboxyl­ate groups from different ligands at the basal plan...

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Detalles Bibliográficos
Autores principales: Guo, Junfang, Yan, Guoping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470168/
https://www.ncbi.nlm.nih.gov/pubmed/23125612
http://dx.doi.org/10.1107/S1600536812039839
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author Guo, Junfang
Yan, Guoping
author_facet Guo, Junfang
Yan, Guoping
author_sort Guo, Junfang
collection PubMed
description The title complex, [Cu(2)(C(16)H(10)NO(2))(4)(CH(3)OH)(2)], consists of centrosymmetric wheel-shaped dinuclear neutral mol­ecules in which each Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by four O atoms of carboxyl­ate groups from different ligands at the basal plane and an O atom of a methanol mol­ecule at the axial position. In the crystal, the dinuclear complex mol­ecules are linked into one-dimensional supra­molecular columns parallel to the b axis by O—H⋯N hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.7259 (11) Å].
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spelling pubmed-34701682012-11-02 Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)] Guo, Junfang Yan, Guoping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(16)H(10)NO(2))(4)(CH(3)OH)(2)], consists of centrosymmetric wheel-shaped dinuclear neutral mol­ecules in which each Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by four O atoms of carboxyl­ate groups from different ligands at the basal plane and an O atom of a methanol mol­ecule at the axial position. In the crystal, the dinuclear complex mol­ecules are linked into one-dimensional supra­molecular columns parallel to the b axis by O—H⋯N hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.7259 (11) Å]. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470168/ /pubmed/23125612 http://dx.doi.org/10.1107/S1600536812039839 Text en © Guo and Yan 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Junfang
Yan, Guoping
Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)]
title Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)]
title_full Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)]
title_fullStr Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)]
title_full_unstemmed Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)]
title_short Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) O:O′)bis­[(methanol-κO)copper(II)]
title_sort tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ(2) o:o′)bis­[(methanol-κo)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470168/
https://www.ncbi.nlm.nih.gov/pubmed/23125612
http://dx.doi.org/10.1107/S1600536812039839
work_keys_str_mv AT guojunfang tetrakism2phenylquinoline4carboxylatok2oobismethanolkocopperii
AT yanguoping tetrakism2phenylquinoline4carboxylatok2oobismethanolkocopperii

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