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catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2) N (4):N (4′)]] monohydrate]
In the title complex, {[Zn(NCS)(2)(C(15)H(15)N(9))(2)]·H(2)O}(n), the Zn(II) ion is located on an inversion centre and is six-coordinated in a distorted octahedral geometry, coordinated by N atoms from four bridging 1,3,5-tris(1,2,4-triazol-1-ylmethyl)benzene (ttmb) ligands and two terminal SCN(−...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470170/ https://www.ncbi.nlm.nih.gov/pubmed/23125614 http://dx.doi.org/10.1107/S1600536812039256 |
| _version_ | 1782246211225387008 |
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| author | Li, Qing-Xia Shi, Xian-Ju Chen, Lai-Cheng |
| author_facet | Li, Qing-Xia Shi, Xian-Ju Chen, Lai-Cheng |
| author_sort | Li, Qing-Xia |
| collection | PubMed |
| description | In the title complex, {[Zn(NCS)(2)(C(15)H(15)N(9))(2)]·H(2)O}(n), the Zn(II) ion is located on an inversion centre and is six-coordinated in a distorted octahedral geometry, coordinated by N atoms from four bridging 1,3,5-tris(1,2,4-triazol-1-ylmethyl)benzene (ttmb) ligands and two terminal SCN(−) counter-anions. Two of the three triazol groups in each ttmb ligand link the Zn(II) atoms, forming a looped-chain structure along [0-11]. The lattice water molecule shows half-occupancy due to disorder around an inversion centre. |
| format | Online Article Text |
| id | pubmed-3470170 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34701702012-11-02 catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2) N (4):N (4′)]] monohydrate] Li, Qing-Xia Shi, Xian-Ju Chen, Lai-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Zn(NCS)(2)(C(15)H(15)N(9))(2)]·H(2)O}(n), the Zn(II) ion is located on an inversion centre and is six-coordinated in a distorted octahedral geometry, coordinated by N atoms from four bridging 1,3,5-tris(1,2,4-triazol-1-ylmethyl)benzene (ttmb) ligands and two terminal SCN(−) counter-anions. Two of the three triazol groups in each ttmb ligand link the Zn(II) atoms, forming a looped-chain structure along [0-11]. The lattice water molecule shows half-occupancy due to disorder around an inversion centre. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470170/ /pubmed/23125614 http://dx.doi.org/10.1107/S1600536812039256 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Qing-Xia Shi, Xian-Ju Chen, Lai-Cheng catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2) N (4):N (4′)]] monohydrate] |
| title |
catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2)
N
(4):N
(4′)]] monohydrate] |
| title_full |
catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2)
N
(4):N
(4′)]] monohydrate] |
| title_fullStr |
catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2)
N
(4):N
(4′)]] monohydrate] |
| title_full_unstemmed |
catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2)
N
(4):N
(4′)]] monohydrate] |
| title_short |
catena-Poly[[[bis(thiocyanato-κN)zinc]bis[μ-1,3,5-tris(1H-1,2,4-triazol-1-ylmethyl)benzene-κ(2)
N
(4):N
(4′)]] monohydrate] |
| title_sort | catena-poly[[[bis(thiocyanato-κn)zinc]bis[μ-1,3,5-tris(1h-1,2,4-triazol-1-ylmethyl)benzene-κ(2)
n
(4):n
(4′)]] monohydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470170/ https://www.ncbi.nlm.nih.gov/pubmed/23125614 http://dx.doi.org/10.1107/S1600536812039256 |
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