Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]

In the centrosymmetric dinuclear title compound, [Hg(2)Cl(4)(C(6)H(8)N(2))(2)], the Hg(II) ion is four-coordinated by one pyridine N atom from a 2-amino-4-methyl­pyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetra­hedral geometry is formed around each Hg(II) ion. The c...

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Detalles Bibliográficos
Autores principales: Tadjarodi, Azadeh, Bijanzad, Keyvan, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470171/
https://www.ncbi.nlm.nih.gov/pubmed/23125615
http://dx.doi.org/10.1107/S1600536812039803
Descripción
Sumario:In the centrosymmetric dinuclear title compound, [Hg(2)Cl(4)(C(6)H(8)N(2))(2)], the Hg(II) ion is four-coordinated by one pyridine N atom from a 2-amino-4-methyl­pyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetra­hedral geometry is formed around each Hg(II) ion. The crystal packing is stabilized by intra- and inter­molecular N—H⋯Cl hydrogen bonding. There are also π–π stacking inter­actions in the structure, with centroid-to-centroid distances of 3.594 (6) Å.

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