Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]

In the centrosymmetric dinuclear title compound, [Hg(2)Cl(4)(C(6)H(8)N(2))(2)], the Hg(II) ion is four-coordinated by one pyridine N atom from a 2-amino-4-methyl­pyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetra­hedral geometry is formed around each Hg(II) ion. The c...

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Detalles Bibliográficos
Autores principales: Tadjarodi, Azadeh, Bijanzad, Keyvan, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470171/
https://www.ncbi.nlm.nih.gov/pubmed/23125615
http://dx.doi.org/10.1107/S1600536812039803
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author Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
author_facet Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
author_sort Tadjarodi, Azadeh
collection PubMed
description In the centrosymmetric dinuclear title compound, [Hg(2)Cl(4)(C(6)H(8)N(2))(2)], the Hg(II) ion is four-coordinated by one pyridine N atom from a 2-amino-4-methyl­pyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetra­hedral geometry is formed around each Hg(II) ion. The crystal packing is stabilized by intra- and inter­molecular N—H⋯Cl hydrogen bonding. There are also π–π stacking inter­actions in the structure, with centroid-to-centroid distances of 3.594 (6) Å.
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spelling pubmed-34701712012-11-02 Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)] Tadjarodi, Azadeh Bijanzad, Keyvan Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Hg(2)Cl(4)(C(6)H(8)N(2))(2)], the Hg(II) ion is four-coordinated by one pyridine N atom from a 2-amino-4-methyl­pyridine ligand, one terminal Cl atom and two bridging Cl atoms. A distorted tetra­hedral geometry is formed around each Hg(II) ion. The crystal packing is stabilized by intra- and inter­molecular N—H⋯Cl hydrogen bonding. There are also π–π stacking inter­actions in the structure, with centroid-to-centroid distances of 3.594 (6) Å. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470171/ /pubmed/23125615 http://dx.doi.org/10.1107/S1600536812039803 Text en © Tadjarodi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadjarodi, Azadeh
Bijanzad, Keyvan
Notash, Behrouz
Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]
title Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]
title_full Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]
title_fullStr Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]
title_full_unstemmed Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]
title_short Di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κN)­chloridomercury(II)]
title_sort di-μ-chlorido-bis­[(2-amino-4-methyl­pyridine-κn)­chloridomercury(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470171/
https://www.ncbi.nlm.nih.gov/pubmed/23125615
http://dx.doi.org/10.1107/S1600536812039803
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