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Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium]

In the title compound, [CuK(2)(C(3)N(2)O(3))(2)(H(2)O)(3)](n), the Cu(2+) atom is in a distorted square-pyramidal coordination geometry. Two N atoms belonging to the oxime groups and two O atoms belonging to the carboxyl­ate groups of two trans-disposed doubly deprotonated residues of 2-cyano-2-(hy­...

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Autores principales: Golenya, Irina A., Izotova, Yulia A., Usenko, Natalia I., Kalibabchuk, Valentina A., Kotova, Natalia V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470173/
https://www.ncbi.nlm.nih.gov/pubmed/23125617
http://dx.doi.org/10.1107/S1600536812036641
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author Golenya, Irina A.
Izotova, Yulia A.
Usenko, Natalia I.
Kalibabchuk, Valentina A.
Kotova, Natalia V.
author_facet Golenya, Irina A.
Izotova, Yulia A.
Usenko, Natalia I.
Kalibabchuk, Valentina A.
Kotova, Natalia V.
author_sort Golenya, Irina A.
collection PubMed
description In the title compound, [CuK(2)(C(3)N(2)O(3))(2)(H(2)O)(3)](n), the Cu(2+) atom is in a distorted square-pyramidal coordination geometry. Two N atoms belonging to the oxime groups and two O atoms belonging to the carboxyl­ate groups of two trans-disposed doubly deprotonated residues of 2-cyano-2-(hy­droxy­imino)­acetic acid make up the basal plane and the apical position is occupied by the water mol­ecule. The neighboring Cu-containing moieties are linked into a three-dimensional framework by K—O and K—N contacts formed by two potassium cations with the carboxyl­ate and the oxime O atoms and the nitrile N atoms of the ligand. The environments of the K(+) cations are complemented to octa- and nona­coordinated, by K—O contacts with H(2)O mol­ecules. The crystal structure features O—H⋯O hydrogen bonds.
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spelling pubmed-34701732012-11-02 Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium] Golenya, Irina A. Izotova, Yulia A. Usenko, Natalia I. Kalibabchuk, Valentina A. Kotova, Natalia V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuK(2)(C(3)N(2)O(3))(2)(H(2)O)(3)](n), the Cu(2+) atom is in a distorted square-pyramidal coordination geometry. Two N atoms belonging to the oxime groups and two O atoms belonging to the carboxyl­ate groups of two trans-disposed doubly deprotonated residues of 2-cyano-2-(hy­droxy­imino)­acetic acid make up the basal plane and the apical position is occupied by the water mol­ecule. The neighboring Cu-containing moieties are linked into a three-dimensional framework by K—O and K—N contacts formed by two potassium cations with the carboxyl­ate and the oxime O atoms and the nitrile N atoms of the ligand. The environments of the K(+) cations are complemented to octa- and nona­coordinated, by K—O contacts with H(2)O mol­ecules. The crystal structure features O—H⋯O hydrogen bonds. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470173/ /pubmed/23125617 http://dx.doi.org/10.1107/S1600536812036641 Text en © Golenya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Golenya, Irina A.
Izotova, Yulia A.
Usenko, Natalia I.
Kalibabchuk, Valentina A.
Kotova, Natalia V.
Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium]
title Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium]
title_full Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium]
title_fullStr Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium]
title_full_unstemmed Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium]
title_short Poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(II)dipotassium]
title_sort poly[μ-aqua-diaquabis­[μ-2-cyano-2-(oxidoimino)­acetato]­copper(ii)dipotassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470173/
https://www.ncbi.nlm.nih.gov/pubmed/23125617
http://dx.doi.org/10.1107/S1600536812036641
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