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Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium]
In the title compound, [CuK(2)(C(3)N(2)O(3))(2)(H(2)O)(3)](n), the Cu(2+) atom is in a distorted square-pyramidal coordination geometry. Two N atoms belonging to the oxime groups and two O atoms belonging to the carboxylate groups of two trans-disposed doubly deprotonated residues of 2-cyano-2-(hy...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470173/ https://www.ncbi.nlm.nih.gov/pubmed/23125617 http://dx.doi.org/10.1107/S1600536812036641 |
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author | Golenya, Irina A. Izotova, Yulia A. Usenko, Natalia I. Kalibabchuk, Valentina A. Kotova, Natalia V. |
author_facet | Golenya, Irina A. Izotova, Yulia A. Usenko, Natalia I. Kalibabchuk, Valentina A. Kotova, Natalia V. |
author_sort | Golenya, Irina A. |
collection | PubMed |
description | In the title compound, [CuK(2)(C(3)N(2)O(3))(2)(H(2)O)(3)](n), the Cu(2+) atom is in a distorted square-pyramidal coordination geometry. Two N atoms belonging to the oxime groups and two O atoms belonging to the carboxylate groups of two trans-disposed doubly deprotonated residues of 2-cyano-2-(hydroxyimino)acetic acid make up the basal plane and the apical position is occupied by the water molecule. The neighboring Cu-containing moieties are linked into a three-dimensional framework by K—O and K—N contacts formed by two potassium cations with the carboxylate and the oxime O atoms and the nitrile N atoms of the ligand. The environments of the K(+) cations are complemented to octa- and nonacoordinated, by K—O contacts with H(2)O molecules. The crystal structure features O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3470173 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34701732012-11-02 Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium] Golenya, Irina A. Izotova, Yulia A. Usenko, Natalia I. Kalibabchuk, Valentina A. Kotova, Natalia V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuK(2)(C(3)N(2)O(3))(2)(H(2)O)(3)](n), the Cu(2+) atom is in a distorted square-pyramidal coordination geometry. Two N atoms belonging to the oxime groups and two O atoms belonging to the carboxylate groups of two trans-disposed doubly deprotonated residues of 2-cyano-2-(hydroxyimino)acetic acid make up the basal plane and the apical position is occupied by the water molecule. The neighboring Cu-containing moieties are linked into a three-dimensional framework by K—O and K—N contacts formed by two potassium cations with the carboxylate and the oxime O atoms and the nitrile N atoms of the ligand. The environments of the K(+) cations are complemented to octa- and nonacoordinated, by K—O contacts with H(2)O molecules. The crystal structure features O—H⋯O hydrogen bonds. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470173/ /pubmed/23125617 http://dx.doi.org/10.1107/S1600536812036641 Text en © Golenya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Golenya, Irina A. Izotova, Yulia A. Usenko, Natalia I. Kalibabchuk, Valentina A. Kotova, Natalia V. Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium] |
title | Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium] |
title_full | Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium] |
title_fullStr | Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium] |
title_full_unstemmed | Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium] |
title_short | Poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(II)dipotassium] |
title_sort | poly[μ-aqua-diaquabis[μ-2-cyano-2-(oxidoimino)acetato]copper(ii)dipotassium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470173/ https://www.ncbi.nlm.nih.gov/pubmed/23125617 http://dx.doi.org/10.1107/S1600536812036641 |
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