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Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)

The asymmetric unit of the title compound, [Zn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(10)N(2)·2H(2)O, comprises half of a centrosymmetric complex dimer, half of a 1,2-bis­(pyridin-4-yl)ethene mol­ecule, which lies across an inversion centre, and one lattice water mol­ecule. Carboxyl­ate groups of two...

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Detalles Bibliográficos
Autores principales: Hwang, In Hong, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470174/
https://www.ncbi.nlm.nih.gov/pubmed/23125618
http://dx.doi.org/10.1107/S1600536812039761
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author Hwang, In Hong
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Hwang, In Hong
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Hwang, In Hong
collection PubMed
description The asymmetric unit of the title compound, [Zn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(10)N(2)·2H(2)O, comprises half of a centrosymmetric complex dimer, half of a 1,2-bis­(pyridin-4-yl)ethene mol­ecule, which lies across an inversion centre, and one lattice water mol­ecule. Carboxyl­ate groups of two dianionic citrate ligands bridge two Zn(II) ions to give the cyclic dimer, with each Zn(II) ion coordinated by four O atoms from the chelating citrate ligand (one hy­droxy and three carboxyl­ate, with one bridging) and two water O atoms, forming a distorted octa­hedral environment [Zn—O = 2.040 (3)–2.244 (3) Å]. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds involving hy­droxy groups and both coordinating and lattice water mol­ecules link the dimers to give a three-dimensional framework structure.
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spelling pubmed-34701742012-11-02 Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2) Hwang, In Hong Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(10)N(2)·2H(2)O, comprises half of a centrosymmetric complex dimer, half of a 1,2-bis­(pyridin-4-yl)ethene mol­ecule, which lies across an inversion centre, and one lattice water mol­ecule. Carboxyl­ate groups of two dianionic citrate ligands bridge two Zn(II) ions to give the cyclic dimer, with each Zn(II) ion coordinated by four O atoms from the chelating citrate ligand (one hy­droxy and three carboxyl­ate, with one bridging) and two water O atoms, forming a distorted octa­hedral environment [Zn—O = 2.040 (3)–2.244 (3) Å]. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds involving hy­droxy groups and both coordinating and lattice water mol­ecules link the dimers to give a three-dimensional framework structure. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470174/ /pubmed/23125618 http://dx.doi.org/10.1107/S1600536812039761 Text en © Hwang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hwang, In Hong
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)
title Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)
title_full Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)
title_fullStr Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)
title_full_unstemmed Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)
title_short Bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)
title_sort bis(μ-3-carb­oxy-2-hy­droxy­propane-1,2-dicarboxyl­ato)bis(diaquazinc)–1,2-bis­(pyridin-4-yl)ethene–water (1/1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470174/
https://www.ncbi.nlm.nih.gov/pubmed/23125618
http://dx.doi.org/10.1107/S1600536812039761
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