(Acetato-κ(2) O,O′)[2′-(di-tert-butyl­phosphanyl)-1,1′-biphenyl-κ(2) P,C (2)]palladium(II)

The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra­molecular C—H⋯O inter­action is noted. The cryst...

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Detalles Bibliográficos
Autores principales: Arderne, Charmaine, Holzapfel, Cedric W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470176/
https://www.ncbi.nlm.nih.gov/pubmed/23125620
http://dx.doi.org/10.1107/S1600536812040068
Descripción
Sumario:The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra­molecular C—H⋯O inter­action is noted. The crystal studied was a racemic twin.

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