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(Acetato-κ(2) O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2) P,C (2)]palladium(II)
The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intramolecular C—H⋯O interaction is noted. The cryst...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470176/ https://www.ncbi.nlm.nih.gov/pubmed/23125620 http://dx.doi.org/10.1107/S1600536812040068 |
| _version_ | 1782246212713316352 |
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| author | Arderne, Charmaine Holzapfel, Cedric W. |
| author_facet | Arderne, Charmaine Holzapfel, Cedric W. |
| author_sort | Arderne, Charmaine |
| collection | PubMed |
| description | The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intramolecular C—H⋯O interaction is noted. The crystal studied was a racemic twin. |
| format | Online Article Text |
| id | pubmed-3470176 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34701762012-11-02 (Acetato-κ(2) O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2) P,C (2)]palladium(II) Arderne, Charmaine Holzapfel, Cedric W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intramolecular C—H⋯O interaction is noted. The crystal studied was a racemic twin. International Union of Crystallography 2012-09-26 /pmc/articles/PMC3470176/ /pubmed/23125620 http://dx.doi.org/10.1107/S1600536812040068 Text en © Arderne and Holzapfel 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Arderne, Charmaine Holzapfel, Cedric W. (Acetato-κ(2) O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2) P,C (2)]palladium(II) |
| title | (Acetato-κ(2)
O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2)
P,C
(2)]palladium(II) |
| title_full | (Acetato-κ(2)
O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2)
P,C
(2)]palladium(II) |
| title_fullStr | (Acetato-κ(2)
O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2)
P,C
(2)]palladium(II) |
| title_full_unstemmed | (Acetato-κ(2)
O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2)
P,C
(2)]palladium(II) |
| title_short | (Acetato-κ(2)
O,O′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2)
P,C
(2)]palladium(II) |
| title_sort | (acetato-κ(2)
o,o′)[2′-(di-tert-butylphosphanyl)-1,1′-biphenyl-κ(2)
p,c
(2)]palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470176/ https://www.ncbi.nlm.nih.gov/pubmed/23125620 http://dx.doi.org/10.1107/S1600536812040068 |
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