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μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]

The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydro­thermally. The binuclear complex mol­ecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C—C bond. The Pb(II) ion is hepta­coordinated by the O atom of one wate...

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Autores principales: Pan, Gang-Hong, Tang, Jin-Niu, Huang, Zhong-Jing, Li, Long, Zhang, Chun-Mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470178/
https://www.ncbi.nlm.nih.gov/pubmed/23125622
http://dx.doi.org/10.1107/S1600536812040196
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author Pan, Gang-Hong
Tang, Jin-Niu
Huang, Zhong-Jing
Li, Long
Zhang, Chun-Mei
author_facet Pan, Gang-Hong
Tang, Jin-Niu
Huang, Zhong-Jing
Li, Long
Zhang, Chun-Mei
author_sort Pan, Gang-Hong
collection PubMed
description The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydro­thermally. The binuclear complex mol­ecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C—C bond. The Pb(II) ion is hepta­coordinated by the O atom of one water mol­ecule, two oxalate O atoms, two nitrate O atoms and two 2,2′-bipyridine N atoms, forming an irregular coordination environemnt. Inter­molecular O—H⋯O hydrogen bonds between water mol­ecules and oxalate and nitrate ions result in the formation of layers parallel to (010). π–π inter­actions between pyridine rings in adjacent layers, with centroid–centroid distances of 3.584 (2) Å, stabilize the structural set-up.
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spelling pubmed-34701782012-11-02 μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)] Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Li, Long Zhang, Chun-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydro­thermally. The binuclear complex mol­ecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C—C bond. The Pb(II) ion is hepta­coordinated by the O atom of one water mol­ecule, two oxalate O atoms, two nitrate O atoms and two 2,2′-bipyridine N atoms, forming an irregular coordination environemnt. Inter­molecular O—H⋯O hydrogen bonds between water mol­ecules and oxalate and nitrate ions result in the formation of layers parallel to (010). π–π inter­actions between pyridine rings in adjacent layers, with centroid–centroid distances of 3.584 (2) Å, stabilize the structural set-up. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470178/ /pubmed/23125622 http://dx.doi.org/10.1107/S1600536812040196 Text en © Pan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pan, Gang-Hong
Tang, Jin-Niu
Huang, Zhong-Jing
Li, Long
Zhang, Chun-Mei
μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]
title μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]
title_full μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]
title_fullStr μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]
title_full_unstemmed μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]
title_short μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis­[aqua­(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]
title_sort μ-oxalato-κ(4) o (1),o (2):o (1′),o (2′)-bis­[aqua­(2,2′-bipyridine-κn)(nitrato-κ(2) o,o′)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470178/
https://www.ncbi.nlm.nih.gov/pubmed/23125622
http://dx.doi.org/10.1107/S1600536812040196
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