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μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)]
The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydrothermally. The binuclear complex molecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C—C bond. The Pb(II) ion is heptacoordinated by the O atom of one wate...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470178/ https://www.ncbi.nlm.nih.gov/pubmed/23125622 http://dx.doi.org/10.1107/S1600536812040196 |
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author | Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Li, Long Zhang, Chun-Mei |
author_facet | Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Li, Long Zhang, Chun-Mei |
author_sort | Pan, Gang-Hong |
collection | PubMed |
description | The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydrothermally. The binuclear complex molecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C—C bond. The Pb(II) ion is heptacoordinated by the O atom of one water molecule, two oxalate O atoms, two nitrate O atoms and two 2,2′-bipyridine N atoms, forming an irregular coordination environemnt. Intermolecular O—H⋯O hydrogen bonds between water molecules and oxalate and nitrate ions result in the formation of layers parallel to (010). π–π interactions between pyridine rings in adjacent layers, with centroid–centroid distances of 3.584 (2) Å, stabilize the structural set-up. |
format | Online Article Text |
id | pubmed-3470178 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34701782012-11-02 μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)] Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Li, Long Zhang, Chun-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pb(2)(C(2)O(4))(NO(3))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], was synthesized hydrothermally. The binuclear complex molecule is centrosymmetric, the inversion centre being located at the mid-point of the oxalate C—C bond. The Pb(II) ion is heptacoordinated by the O atom of one water molecule, two oxalate O atoms, two nitrate O atoms and two 2,2′-bipyridine N atoms, forming an irregular coordination environemnt. Intermolecular O—H⋯O hydrogen bonds between water molecules and oxalate and nitrate ions result in the formation of layers parallel to (010). π–π interactions between pyridine rings in adjacent layers, with centroid–centroid distances of 3.584 (2) Å, stabilize the structural set-up. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470178/ /pubmed/23125622 http://dx.doi.org/10.1107/S1600536812040196 Text en © Pan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Pan, Gang-Hong Tang, Jin-Niu Huang, Zhong-Jing Li, Long Zhang, Chun-Mei μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2) O,O′)lead(II)] |
title | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2)
O,O′)lead(II)] |
title_full | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2)
O,O′)lead(II)] |
title_fullStr | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2)
O,O′)lead(II)] |
title_full_unstemmed | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2)
O,O′)lead(II)] |
title_short | μ-Oxalato-κ(4)
O
(1),O
(2):O
(1′),O
(2′)-bis[aqua(2,2′-bipyridine-κN)(nitrato-κ(2)
O,O′)lead(II)] |
title_sort | μ-oxalato-κ(4)
o
(1),o
(2):o
(1′),o
(2′)-bis[aqua(2,2′-bipyridine-κn)(nitrato-κ(2)
o,o′)lead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470178/ https://www.ncbi.nlm.nih.gov/pubmed/23125622 http://dx.doi.org/10.1107/S1600536812040196 |
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