cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate

In the title compound, [VClO(C(12)H(12)N(2))(2)]Cl·C(2)H(5)OH·H(2)O, the V(IV) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two 4,4′-dimethyl-2,2′-bipyridine ligands, one O atom and one Cl atom. In the crystal, O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π conta...

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Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara, Golabi, Elyas, Gholamzadeh, Mohammad Amin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470179/
https://www.ncbi.nlm.nih.gov/pubmed/23125623
http://dx.doi.org/10.1107/S1600536812040251
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
Golabi, Elyas
Gholamzadeh, Mohammad Amin
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
Golabi, Elyas
Gholamzadeh, Mohammad Amin
author_sort Shirvan, Sadif A.
collection PubMed
description In the title compound, [VClO(C(12)H(12)N(2))(2)]Cl·C(2)H(5)OH·H(2)O, the V(IV) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two 4,4′-dimethyl-2,2′-bipyridine ligands, one O atom and one Cl atom. In the crystal, O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.7236 (17) and 3.6026 (19) Å] stabilize the structure. Intra­molecular C—H⋯O and C—H⋯Cl hydrogen bonds are also present.
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spelling pubmed-34701792012-11-02 cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate Shirvan, Sadif A. Haydari Dezfuli, Sara Golabi, Elyas Gholamzadeh, Mohammad Amin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [VClO(C(12)H(12)N(2))(2)]Cl·C(2)H(5)OH·H(2)O, the V(IV) atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two 4,4′-dimethyl-2,2′-bipyridine ligands, one O atom and one Cl atom. In the crystal, O—H⋯Cl, C—H⋯O and C—H⋯Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.7236 (17) and 3.6026 (19) Å] stabilize the structure. Intra­molecular C—H⋯O and C—H⋯Cl hydrogen bonds are also present. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470179/ /pubmed/23125623 http://dx.doi.org/10.1107/S1600536812040251 Text en © Shirvan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Golabi, Elyas
Gholamzadeh, Mohammad Amin
cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
title cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
title_full cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
title_fullStr cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
title_full_unstemmed cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
title_short cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate
title_sort cis-chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)oxidovanadium(iv) chloride ethanol monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470179/
https://www.ncbi.nlm.nih.gov/pubmed/23125623
http://dx.doi.org/10.1107/S1600536812040251
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