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μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate
In the title solvate, [Rh(2)(C(22)H(18)N(2)O(2))(C(8)H(12))(2)]·CH(2)Cl(2), each organometallic molecule is composed of two Rh(I) cations, the tetradentate dianion α,α′-bis(salicylaldiminato)-m-xylene and two 1,5-cyclooctadiene (COD) ligands. Each Rh(I) atom is coordinated by one O atom [Rh—O =...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470182/ https://www.ncbi.nlm.nih.gov/pubmed/23125626 http://dx.doi.org/10.1107/S1600536812040603 |
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author | Gregory, Stacie Laxman, Ravi K. Fronczek, Frank R. Maverick, Andrew W. Watkins, Steven F. |
author_facet | Gregory, Stacie Laxman, Ravi K. Fronczek, Frank R. Maverick, Andrew W. Watkins, Steven F. |
author_sort | Gregory, Stacie |
collection | PubMed |
description | In the title solvate, [Rh(2)(C(22)H(18)N(2)O(2))(C(8)H(12))(2)]·CH(2)Cl(2), each organometallic molecule is composed of two Rh(I) cations, the tetradentate dianion α,α′-bis(salicylaldiminato)-m-xylene and two 1,5-cyclooctadiene (COD) ligands. Each Rh(I) atom is coordinated by one O atom [Rh—O = 2.044 (2) and 2.026 (2) Å], one N atom [Rh—N = 2.083 (2) and 2.090 (2) Å], and one COD ligand via two η(2)-bonds, each directed toward the mid-point of a C=C bond (Cg): Rh—Cg = 2.007 (2), 2.013 (2), 2.000 (2) and 2.021 (2) Å. Each Rh(I) atom has a quasi-square-planar coordination geometry, with average r.m.s. deviations of 0.159 (1) and 0.204 (1) Å from the mean planes defined by Rh and the termini of its four coordinating bonds. The two COD ligands have quasi-C (2) symmetry, twisted from ideal C (2v) symmetry by 30.0 (3) and −33.1 (3)°, and are quasi-enantiomers of one another. The intramolecular Rh⋯Rh distance of 5.9432 (3) Å suggests that there is no direct metal–metal interaction. |
format | Online Article Text |
id | pubmed-3470182 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34701822012-11-02 μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate Gregory, Stacie Laxman, Ravi K. Fronczek, Frank R. Maverick, Andrew W. Watkins, Steven F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvate, [Rh(2)(C(22)H(18)N(2)O(2))(C(8)H(12))(2)]·CH(2)Cl(2), each organometallic molecule is composed of two Rh(I) cations, the tetradentate dianion α,α′-bis(salicylaldiminato)-m-xylene and two 1,5-cyclooctadiene (COD) ligands. Each Rh(I) atom is coordinated by one O atom [Rh—O = 2.044 (2) and 2.026 (2) Å], one N atom [Rh—N = 2.083 (2) and 2.090 (2) Å], and one COD ligand via two η(2)-bonds, each directed toward the mid-point of a C=C bond (Cg): Rh—Cg = 2.007 (2), 2.013 (2), 2.000 (2) and 2.021 (2) Å. Each Rh(I) atom has a quasi-square-planar coordination geometry, with average r.m.s. deviations of 0.159 (1) and 0.204 (1) Å from the mean planes defined by Rh and the termini of its four coordinating bonds. The two COD ligands have quasi-C (2) symmetry, twisted from ideal C (2v) symmetry by 30.0 (3) and −33.1 (3)°, and are quasi-enantiomers of one another. The intramolecular Rh⋯Rh distance of 5.9432 (3) Å suggests that there is no direct metal–metal interaction. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470182/ /pubmed/23125626 http://dx.doi.org/10.1107/S1600536812040603 Text en © Gregory et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gregory, Stacie Laxman, Ravi K. Fronczek, Frank R. Maverick, Andrew W. Watkins, Steven F. μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate |
title | μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate |
title_full | μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate |
title_fullStr | μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate |
title_full_unstemmed | μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate |
title_short | μ(2)-m-Xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate |
title_sort | μ(2)-m-xylylenebis(salicylaldiminato)-bis(η(4)-1,5-cyclooctadiene)dirhodium(i) dichloromethane solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470182/ https://www.ncbi.nlm.nih.gov/pubmed/23125626 http://dx.doi.org/10.1107/S1600536812040603 |
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