N-Ferrocenylmethyl-2-nitro­aniline

In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2)O(2))], the two cyclo­penta­dienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitro­benzenamine group, which is essentially perpend...

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Autores principales: Rahim, Oumelkheir, Khelef, Abdelhamid, Terki, Belgacem, Mahboub, Mohammed Sadok, Lanez, Touhami
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470183/
https://www.ncbi.nlm.nih.gov/pubmed/23125627
http://dx.doi.org/10.1107/S1600536812039177
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author Rahim, Oumelkheir
Khelef, Abdelhamid
Terki, Belgacem
Mahboub, Mohammed Sadok
Lanez, Touhami
author_facet Rahim, Oumelkheir
Khelef, Abdelhamid
Terki, Belgacem
Mahboub, Mohammed Sadok
Lanez, Touhami
author_sort Rahim, Oumelkheir
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2)O(2))], the two cyclo­penta­dienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitro­benzenamine group, which is essentially perpendicular to the substituted cyclo­penta­dienyl ring, with an N—C(H(2))—C—C torsion angle of 89.8 (2)°. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds occur. In the crystal, weak C—H⋯O hydrogen bonds link adjacent mol­ecules.
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spelling pubmed-34701832012-11-02 N-Ferrocenylmethyl-2-nitro­aniline Rahim, Oumelkheir Khelef, Abdelhamid Terki, Belgacem Mahboub, Mohammed Sadok Lanez, Touhami Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(12)H(11)N(2)O(2))], the two cyclo­penta­dienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitro­benzenamine group, which is essentially perpendicular to the substituted cyclo­penta­dienyl ring, with an N—C(H(2))—C—C torsion angle of 89.8 (2)°. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds occur. In the crystal, weak C—H⋯O hydrogen bonds link adjacent mol­ecules. International Union of Crystallography 2012-09-29 /pmc/articles/PMC3470183/ /pubmed/23125627 http://dx.doi.org/10.1107/S1600536812039177 Text en © Rahim et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rahim, Oumelkheir
Khelef, Abdelhamid
Terki, Belgacem
Mahboub, Mohammed Sadok
Lanez, Touhami
N-Ferrocenylmethyl-2-nitro­aniline
title N-Ferrocenylmethyl-2-nitro­aniline
title_full N-Ferrocenylmethyl-2-nitro­aniline
title_fullStr N-Ferrocenylmethyl-2-nitro­aniline
title_full_unstemmed N-Ferrocenylmethyl-2-nitro­aniline
title_short N-Ferrocenylmethyl-2-nitro­aniline
title_sort n-ferrocenylmethyl-2-nitro­aniline
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470183/
https://www.ncbi.nlm.nih.gov/pubmed/23125627
http://dx.doi.org/10.1107/S1600536812039177
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