4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate

In the title compound, C(16)H(16)N(4)O(3)·CH(3)OH, the aromatic rings form a dihedral angle of 0.4 (2)°. The nitro group is twisted from the attached benzene ring by 7.5 (2)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link alternating hydrazone and methanol mol­ecules into chains in [100]. The...

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Detalles Bibliográficos
Autores principales: Zhang, Xiyue, Fu, Xiaobo, Tan, Langzhu, Wang, Chaixia, Fan, Weixing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470190/
https://www.ncbi.nlm.nih.gov/pubmed/23125634
http://dx.doi.org/10.1107/S1600536812037063
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author Zhang, Xiyue
Fu, Xiaobo
Tan, Langzhu
Wang, Chaixia
Fan, Weixing
author_facet Zhang, Xiyue
Fu, Xiaobo
Tan, Langzhu
Wang, Chaixia
Fan, Weixing
author_sort Zhang, Xiyue
collection PubMed
description In the title compound, C(16)H(16)N(4)O(3)·CH(3)OH, the aromatic rings form a dihedral angle of 0.4 (2)°. The nitro group is twisted from the attached benzene ring by 7.5 (2)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link alternating hydrazone and methanol mol­ecules into chains in [100]. The crystal packing exhibits π–π inter­actions between aromatic rings from neighbouring chains [centroid–centroid distances = 3.734 (3) and 3.903 (3) Å].
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spelling pubmed-34701902012-11-02 4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate Zhang, Xiyue Fu, Xiaobo Tan, Langzhu Wang, Chaixia Fan, Weixing Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)N(4)O(3)·CH(3)OH, the aromatic rings form a dihedral angle of 0.4 (2)°. The nitro group is twisted from the attached benzene ring by 7.5 (2)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link alternating hydrazone and methanol mol­ecules into chains in [100]. The crystal packing exhibits π–π inter­actions between aromatic rings from neighbouring chains [centroid–centroid distances = 3.734 (3) and 3.903 (3) Å]. International Union of Crystallography 2012-09-01 /pmc/articles/PMC3470190/ /pubmed/23125634 http://dx.doi.org/10.1107/S1600536812037063 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Xiyue
Fu, Xiaobo
Tan, Langzhu
Wang, Chaixia
Fan, Weixing
4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title 4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_full 4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_fullStr 4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_full_unstemmed 4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_short 4-Dimethyl­amino-N′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
title_sort 4-dimethyl­amino-n′-(4-nitro­benzyl­idene)benzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470190/
https://www.ncbi.nlm.nih.gov/pubmed/23125634
http://dx.doi.org/10.1107/S1600536812037063
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