Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate

The title compound, C(17)H(19)NO(4), which is a non-toxic insect growth regulator with the common name fenoxycarb, contains two independent and conformationally different mol­ecules in the asymmetric unit. Although the inter-ring dihedral angles are similar [62.21 (15) and 63.00 (14)°], the side-cha...

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Autores principales: Karpinska, Jolanta, Kuhs, Manuel, Rasmuson, Ake, Erxleben, Andrea, McArdle, Patrick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470196/
https://www.ncbi.nlm.nih.gov/pubmed/23125640
http://dx.doi.org/10.1107/S1600536812037105
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author Karpinska, Jolanta
Kuhs, Manuel
Rasmuson, Ake
Erxleben, Andrea
McArdle, Patrick
author_facet Karpinska, Jolanta
Kuhs, Manuel
Rasmuson, Ake
Erxleben, Andrea
McArdle, Patrick
author_sort Karpinska, Jolanta
collection PubMed
description The title compound, C(17)H(19)NO(4), which is a non-toxic insect growth regulator with the common name fenoxycarb, contains two independent and conformationally different mol­ecules in the asymmetric unit. Although the inter-ring dihedral angles are similar [62.21 (15) and 63.00 (14)°], the side-chain orientations differ. In the crystal, the mol­ecules are linked through N—H⋯O hydrogen-bonding associations, giving chains which extend along [110], while intra- and inter­molecular aromatic C—H⋯π inter­actions give sheet structures parallel to [110].
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spelling pubmed-34701962012-11-02 Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate Karpinska, Jolanta Kuhs, Manuel Rasmuson, Ake Erxleben, Andrea McArdle, Patrick Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(19)NO(4), which is a non-toxic insect growth regulator with the common name fenoxycarb, contains two independent and conformationally different mol­ecules in the asymmetric unit. Although the inter-ring dihedral angles are similar [62.21 (15) and 63.00 (14)°], the side-chain orientations differ. In the crystal, the mol­ecules are linked through N—H⋯O hydrogen-bonding associations, giving chains which extend along [110], while intra- and inter­molecular aromatic C—H⋯π inter­actions give sheet structures parallel to [110]. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470196/ /pubmed/23125640 http://dx.doi.org/10.1107/S1600536812037105 Text en © Karpinska et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karpinska, Jolanta
Kuhs, Manuel
Rasmuson, Ake
Erxleben, Andrea
McArdle, Patrick
Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate
title Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate
title_full Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate
title_fullStr Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate
title_full_unstemmed Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate
title_short Ethyl N-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate
title_sort ethyl n-[2-(4-phen­oxy­phen­oxy)eth­yl]carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470196/
https://www.ncbi.nlm.nih.gov/pubmed/23125640
http://dx.doi.org/10.1107/S1600536812037105
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AT erxlebenandrea ethyln24phenoxyphenoxyethylcarbamate
AT mcardlepatrick ethyln24phenoxyphenoxyethylcarbamate

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