(2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide

The title compound, C(11)H(13)N(3)S, is close to being planar, with a dihedral angle of 9.64 (3)° between the benzene ring and the thio­semicarbazone mean plane, maintained by the presence of π-conjugation in the chain linking the the two systems. In the crystal, N—H⋯S hydrogen bonds form centrosymm...

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Detalles Bibliográficos
Autores principales: Murali Krishna, P., Anilkumar, G. N., Hussain Reddy, K., Kokila, M. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470202/
https://www.ncbi.nlm.nih.gov/pubmed/23125646
http://dx.doi.org/10.1107/S1600536812037397
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author Murali Krishna, P.
Anilkumar, G. N.
Hussain Reddy, K.
Kokila, M. K.
author_facet Murali Krishna, P.
Anilkumar, G. N.
Hussain Reddy, K.
Kokila, M. K.
author_sort Murali Krishna, P.
collection PubMed
description The title compound, C(11)H(13)N(3)S, is close to being planar, with a dihedral angle of 9.64 (3)° between the benzene ring and the thio­semicarbazone mean plane, maintained by the presence of π-conjugation in the chain linking the the two systems. In the crystal, N—H⋯S hydrogen bonds form centrosymmetric dimers through a cyclic association [graph-set R (2) (2)(8)].
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spelling pubmed-34702022012-11-02 (2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide Murali Krishna, P. Anilkumar, G. N. Hussain Reddy, K. Kokila, M. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(13)N(3)S, is close to being planar, with a dihedral angle of 9.64 (3)° between the benzene ring and the thio­semicarbazone mean plane, maintained by the presence of π-conjugation in the chain linking the the two systems. In the crystal, N—H⋯S hydrogen bonds form centrosymmetric dimers through a cyclic association [graph-set R (2) (2)(8)]. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470202/ /pubmed/23125646 http://dx.doi.org/10.1107/S1600536812037397 Text en © Murali Krishna et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Murali Krishna, P.
Anilkumar, G. N.
Hussain Reddy, K.
Kokila, M. K.
(2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide
title (2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide
title_full (2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide
title_fullStr (2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide
title_full_unstemmed (2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide
title_short (2E)-N-Methyl-2-[(2E)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide
title_sort (2e)-n-methyl-2-[(2e)-3-phenyl­prop-2-en-1-yl­idene]hydrazinecarbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470202/
https://www.ncbi.nlm.nih.gov/pubmed/23125646
http://dx.doi.org/10.1107/S1600536812037397
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AT hussainreddyk 2enmethyl22e3phenylprop2en1ylidenehydrazinecarbothioamide
AT kokilamk 2enmethyl22e3phenylprop2en1ylidenehydrazinecarbothioamide

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