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2,6-Dimeth­oxy-9,10-anthraquinone

The title compound, C(16)H(12)O(4), crystallizes with two half-mol­ecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent mol­ecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3)...

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Detalles Bibliográficos
Autores principales: Ohta, Akira, Hattori, Kazuki, Kobayashi, Takashi, Naito, Hiroyoshi, Kawase, Takeshi, Kitamura, Chitoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470203/
https://www.ncbi.nlm.nih.gov/pubmed/23125647
http://dx.doi.org/10.1107/S1600536812037361
Descripción
Sumario:The title compound, C(16)H(12)O(4), crystallizes with two half-mol­ecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent mol­ecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3) and 0.049 (3) Å]. They adopt a conformation in which the C(meth­yl)—O bonds are directed along the mol­ecular short axis [C—C—O—C torsion angles of 179.6 (2) and 178.0 (2)°]. In the crystal, the mol­ecular packing is characterized by a combination of a columnar stacking and a herringbone-like arrangement. The mol­ecules form slipped π-stacks along the b axis, in which there are two kinds of columns differing from each other in their slippage. The inter­planar distances between neighboring mol­ecules are 3.493 (3) for one column and 3.451 (2) Å for the other.