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2,6-Dimeth­oxy-9,10-anthraquinone

The title compound, C(16)H(12)O(4), crystallizes with two half-mol­ecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent mol­ecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3)...

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Autores principales: Ohta, Akira, Hattori, Kazuki, Kobayashi, Takashi, Naito, Hiroyoshi, Kawase, Takeshi, Kitamura, Chitoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470203/
https://www.ncbi.nlm.nih.gov/pubmed/23125647
http://dx.doi.org/10.1107/S1600536812037361
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author Ohta, Akira
Hattori, Kazuki
Kobayashi, Takashi
Naito, Hiroyoshi
Kawase, Takeshi
Kitamura, Chitoshi
author_facet Ohta, Akira
Hattori, Kazuki
Kobayashi, Takashi
Naito, Hiroyoshi
Kawase, Takeshi
Kitamura, Chitoshi
author_sort Ohta, Akira
collection PubMed
description The title compound, C(16)H(12)O(4), crystallizes with two half-mol­ecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent mol­ecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3) and 0.049 (3) Å]. They adopt a conformation in which the C(meth­yl)—O bonds are directed along the mol­ecular short axis [C—C—O—C torsion angles of 179.6 (2) and 178.0 (2)°]. In the crystal, the mol­ecular packing is characterized by a combination of a columnar stacking and a herringbone-like arrangement. The mol­ecules form slipped π-stacks along the b axis, in which there are two kinds of columns differing from each other in their slippage. The inter­planar distances between neighboring mol­ecules are 3.493 (3) for one column and 3.451 (2) Å for the other.
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spelling pubmed-34702032012-11-02 2,6-Dimeth­oxy-9,10-anthraquinone Ohta, Akira Hattori, Kazuki Kobayashi, Takashi Naito, Hiroyoshi Kawase, Takeshi Kitamura, Chitoshi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(12)O(4), crystallizes with two half-mol­ecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent mol­ecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3) and 0.049 (3) Å]. They adopt a conformation in which the C(meth­yl)—O bonds are directed along the mol­ecular short axis [C—C—O—C torsion angles of 179.6 (2) and 178.0 (2)°]. In the crystal, the mol­ecular packing is characterized by a combination of a columnar stacking and a herringbone-like arrangement. The mol­ecules form slipped π-stacks along the b axis, in which there are two kinds of columns differing from each other in their slippage. The inter­planar distances between neighboring mol­ecules are 3.493 (3) for one column and 3.451 (2) Å for the other. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470203/ /pubmed/23125647 http://dx.doi.org/10.1107/S1600536812037361 Text en © Ohta et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ohta, Akira
Hattori, Kazuki
Kobayashi, Takashi
Naito, Hiroyoshi
Kawase, Takeshi
Kitamura, Chitoshi
2,6-Dimeth­oxy-9,10-anthraquinone
title 2,6-Dimeth­oxy-9,10-anthraquinone
title_full 2,6-Dimeth­oxy-9,10-anthraquinone
title_fullStr 2,6-Dimeth­oxy-9,10-anthraquinone
title_full_unstemmed 2,6-Dimeth­oxy-9,10-anthraquinone
title_short 2,6-Dimeth­oxy-9,10-anthraquinone
title_sort 2,6-dimeth­oxy-9,10-anthraquinone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470203/
https://www.ncbi.nlm.nih.gov/pubmed/23125647
http://dx.doi.org/10.1107/S1600536812037361
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