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2,6-Dimethoxy-9,10-anthraquinone
The title compound, C(16)H(12)O(4), crystallizes with two half-molecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent molecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3)...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470203/ https://www.ncbi.nlm.nih.gov/pubmed/23125647 http://dx.doi.org/10.1107/S1600536812037361 |
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author | Ohta, Akira Hattori, Kazuki Kobayashi, Takashi Naito, Hiroyoshi Kawase, Takeshi Kitamura, Chitoshi |
author_facet | Ohta, Akira Hattori, Kazuki Kobayashi, Takashi Naito, Hiroyoshi Kawase, Takeshi Kitamura, Chitoshi |
author_sort | Ohta, Akira |
collection | PubMed |
description | The title compound, C(16)H(12)O(4), crystallizes with two half-molecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent molecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3) and 0.049 (3) Å]. They adopt a conformation in which the C(methyl)—O bonds are directed along the molecular short axis [C—C—O—C torsion angles of 179.6 (2) and 178.0 (2)°]. In the crystal, the molecular packing is characterized by a combination of a columnar stacking and a herringbone-like arrangement. The molecules form slipped π-stacks along the b axis, in which there are two kinds of columns differing from each other in their slippage. The interplanar distances between neighboring molecules are 3.493 (3) for one column and 3.451 (2) Å for the other. |
format | Online Article Text |
id | pubmed-3470203 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34702032012-11-02 2,6-Dimethoxy-9,10-anthraquinone Ohta, Akira Hattori, Kazuki Kobayashi, Takashi Naito, Hiroyoshi Kawase, Takeshi Kitamura, Chitoshi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(12)O(4), crystallizes with two half-molecules in the asymmetric unit, each of which is completed by a crystallographic inversion center. The two crystallographically independent molecules have almost the same geometry and are almost planar [maximum deviations = 0.018 (3) and 0.049 (3) Å]. They adopt a conformation in which the C(methyl)—O bonds are directed along the molecular short axis [C—C—O—C torsion angles of 179.6 (2) and 178.0 (2)°]. In the crystal, the molecular packing is characterized by a combination of a columnar stacking and a herringbone-like arrangement. The molecules form slipped π-stacks along the b axis, in which there are two kinds of columns differing from each other in their slippage. The interplanar distances between neighboring molecules are 3.493 (3) for one column and 3.451 (2) Å for the other. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470203/ /pubmed/23125647 http://dx.doi.org/10.1107/S1600536812037361 Text en © Ohta et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ohta, Akira Hattori, Kazuki Kobayashi, Takashi Naito, Hiroyoshi Kawase, Takeshi Kitamura, Chitoshi 2,6-Dimethoxy-9,10-anthraquinone |
title | 2,6-Dimethoxy-9,10-anthraquinone |
title_full | 2,6-Dimethoxy-9,10-anthraquinone |
title_fullStr | 2,6-Dimethoxy-9,10-anthraquinone |
title_full_unstemmed | 2,6-Dimethoxy-9,10-anthraquinone |
title_short | 2,6-Dimethoxy-9,10-anthraquinone |
title_sort | 2,6-dimethoxy-9,10-anthraquinone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470203/ https://www.ncbi.nlm.nih.gov/pubmed/23125647 http://dx.doi.org/10.1107/S1600536812037361 |
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