6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione

In the title compound, C(16)H(13)BrFN(3)O(2)S, the dihedral angle between the aromatic rings is 2.55 (19)° and the C=N—N=C torsion angle is 178.9 (3)°. The conformation of the thia­zine ring is an envelope, with the S atom displaced by −0.811 (3) Å from the mean plane of the other five atoms (r.m.s....

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Autores principales: Shafiq, Muhammad, Khan, Islam Ullah, Harrison, William T. A., Hussain, Ajaz, Ashraf, Hina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470210/
https://www.ncbi.nlm.nih.gov/pubmed/23125654
http://dx.doi.org/10.1107/S1600536812037403
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author Shafiq, Muhammad
Khan, Islam Ullah
Harrison, William T. A.
Hussain, Ajaz
Ashraf, Hina
author_facet Shafiq, Muhammad
Khan, Islam Ullah
Harrison, William T. A.
Hussain, Ajaz
Ashraf, Hina
author_sort Shafiq, Muhammad
collection PubMed
description In the title compound, C(16)H(13)BrFN(3)O(2)S, the dihedral angle between the aromatic rings is 2.55 (19)° and the C=N—N=C torsion angle is 178.9 (3)°. The conformation of the thia­zine ring is an envelope, with the S atom displaced by −0.811 (3) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.042 Å). In the crystal, C—H⋯O inter­actions link the mol­ecules and weak aromatic π–π stacking between the fluoro­benzene and bromo­benzene rings [centroid–centroid separation = 3.720 (2) Å and inter­planar angle = 2.6 (2)°] is also observed.
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spelling pubmed-34702102012-11-02 6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione Shafiq, Muhammad Khan, Islam Ullah Harrison, William T. A. Hussain, Ajaz Ashraf, Hina Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(13)BrFN(3)O(2)S, the dihedral angle between the aromatic rings is 2.55 (19)° and the C=N—N=C torsion angle is 178.9 (3)°. The conformation of the thia­zine ring is an envelope, with the S atom displaced by −0.811 (3) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.042 Å). In the crystal, C—H⋯O inter­actions link the mol­ecules and weak aromatic π–π stacking between the fluoro­benzene and bromo­benzene rings [centroid–centroid separation = 3.720 (2) Å and inter­planar angle = 2.6 (2)°] is also observed. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470210/ /pubmed/23125654 http://dx.doi.org/10.1107/S1600536812037403 Text en © Shafiq et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Khan, Islam Ullah
Harrison, William T. A.
Hussain, Ajaz
Ashraf, Hina
6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title 6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_full 6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_fullStr 6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_full_unstemmed 6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_short 6-Bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_sort 6-bromo-4-[2-(4-fluoro­benzyl­idene)hydrazin-1-yl­idene]-1-methyl-3,4-dihydro-1h-2λ(6),1-benzothia­zine-2,2-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470210/
https://www.ncbi.nlm.nih.gov/pubmed/23125654
http://dx.doi.org/10.1107/S1600536812037403
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