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2,2′-{[(2,2′-Diethoxy-1,1′-binaphthalene-6,6′-diyl)bis(4,1-phenylene)]bis(methanylylidene)}dimalononitrile
The title compound, C(44)H(30)N(4)O(2), was prepared from 6,6′-dibromo-2,2′-diethoxy-1,1′-binaphthalene through a coupling reaction with 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde followed by a Knoevenagel reaction with malononitrile. The dihedral angle between the symmetry-relate...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470211/ https://www.ncbi.nlm.nih.gov/pubmed/23125655 http://dx.doi.org/10.1107/S1600536812037282 |
Sumario: | The title compound, C(44)H(30)N(4)O(2), was prepared from 6,6′-dibromo-2,2′-diethoxy-1,1′-binaphthalene through a coupling reaction with 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde followed by a Knoevenagel reaction with malononitrile. The dihedral angle between the symmetry-related naphthalene ring systems is 68.82 (8)° while the dihedral angle between the the naphthalene ring system and the adjacent benzene ring is 16.92 (7)°. Four symmetry-independent molecules which are linked by intermolecular C—H⋯π interaction generate the packing motif in the crystal structure. One of the CN groups is disordered over two sets of sites in a 0.60 (2):0.40 (2) ratio. |
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