Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate

In the title compound, C(26)H(31)NO(3), the octa­hydro-1H-isoindole ring is not planar and the two rings are twisted with a C—C—C—C torsion angle of 73.6 (4)°. The six-membered ring has a chair conformation while the five-membered ring has an envelope conformation on the C-atom in position 7a. The H...

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Autores principales: Shang, Zhenhua, Xu, Longpeng, Zheng, Ligang, Zhang, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470212/
https://www.ncbi.nlm.nih.gov/pubmed/23125656
http://dx.doi.org/10.1107/S1600536812037567
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author Shang, Zhenhua
Xu, Longpeng
Zheng, Ligang
Zhang, Yong
author_facet Shang, Zhenhua
Xu, Longpeng
Zheng, Ligang
Zhang, Yong
author_sort Shang, Zhenhua
collection PubMed
description In the title compound, C(26)H(31)NO(3), the octa­hydro-1H-isoindole ring is not planar and the two rings are twisted with a C—C—C—C torsion angle of 73.6 (4)°. The six-membered ring has a chair conformation while the five-membered ring has an envelope conformation on the C-atom in position 7a. The H atoms in the 3a- and 7a-psitions are cis and the H—C—C—H torsion angle is 42.36°.
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spelling pubmed-34702122012-11-02 Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate Shang, Zhenhua Xu, Longpeng Zheng, Ligang Zhang, Yong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(31)NO(3), the octa­hydro-1H-isoindole ring is not planar and the two rings are twisted with a C—C—C—C torsion angle of 73.6 (4)°. The six-membered ring has a chair conformation while the five-membered ring has an envelope conformation on the C-atom in position 7a. The H atoms in the 3a- and 7a-psitions are cis and the H—C—C—H torsion angle is 42.36°. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470212/ /pubmed/23125656 http://dx.doi.org/10.1107/S1600536812037567 Text en © Shang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shang, Zhenhua
Xu, Longpeng
Zheng, Ligang
Zhang, Yong
Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate
title Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate
title_full Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate
title_fullStr Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate
title_full_unstemmed Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate
title_short Benzyl 2-benzyl-4-[(3aS,7aR)-2,3,3a,4,5,6,7,7a-octa­hydro-1H-isoindol-2-yl]-4-oxobutano­ate
title_sort benzyl 2-benzyl-4-[(3as,7ar)-2,3,3a,4,5,6,7,7a-octa­hydro-1h-isoindol-2-yl]-4-oxobutano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470212/
https://www.ncbi.nlm.nih.gov/pubmed/23125656
http://dx.doi.org/10.1107/S1600536812037567
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