Cargando…

(2Z,2′Z)-Diethyl 3,3′-[butane-1,4-diylbis(aza­nedi­yl)]bis­(but-2-enoate)

The whole mol­ecule of the title β-enamino­ester, C(16)H(28)N(2)O(4), is generated by a crystallographic inversion center, situated at the mid-point of the central C—C bond of the 1,4-diamino­butane segment. There are two intra­molecular N—H⋯O hydrogen bonds that generate S(6) ring motifs. This lead...

Descripción completa

Detalles Bibliográficos
Autores principales: Harrad, Mohamed Anouar, Boualy, Brahim, Ali, Mustapha Ait, El Firdoussi, Larbi, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470214/
https://www.ncbi.nlm.nih.gov/pubmed/23125658
http://dx.doi.org/10.1107/S1600536812036823
Descripción
Sumario:The whole mol­ecule of the title β-enamino­ester, C(16)H(28)N(2)O(4), is generated by a crystallographic inversion center, situated at the mid-point of the central C—C bond of the 1,4-diamino­butane segment. There are two intra­molecular N—H⋯O hydrogen bonds that generate S(6) ring motifs. This leads to the Z conformation about the C=C bonds [1.3756 (17) Å]. The mol­ecule is S-shaped with the planar central 1,4-diamino­butane segment [maximum deviation for non H-atoms = 0.0058 (13) Å] being inclined to the ethyl butyl­enonate fragment [C—C—O—C—C=C—C; maximum deviation = 0.0710 (12) Å] by 15.56 (10)°. In the crystal, mol­ecules are linked via C—H⋯O inter­actions, leading to the formation of an undulating two-dimensional network lying parallel to the bc plane.