1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate

In the title salt, C(13)H(19)N(2) (+)·BF(4) (−), an ionic liquid, the butyl and ethyl substituents bonded to the N atoms of the imidazole ring [r.m.s. deviation = 0.019 (1) Å] adopt equatorial positions. The crystal structure exhibits slipped π–π inter­actions between the imidazole and benzene rings...

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Autores principales: Junge, Denise M., Scadova, Derek R., Golen, James A., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470219/
https://www.ncbi.nlm.nih.gov/pubmed/23125663
http://dx.doi.org/10.1107/S1600536812037476
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author Junge, Denise M.
Scadova, Derek R.
Golen, James A.
Jasinski, Jerry P.
author_facet Junge, Denise M.
Scadova, Derek R.
Golen, James A.
Jasinski, Jerry P.
author_sort Junge, Denise M.
collection PubMed
description In the title salt, C(13)H(19)N(2) (+)·BF(4) (−), an ionic liquid, the butyl and ethyl substituents bonded to the N atoms of the imidazole ring [r.m.s. deviation = 0.019 (1) Å] adopt equatorial positions. The crystal structure exhibits slipped π–π inter­actions between the imidazole and benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.529 (2) Å]. In the tetra­fluoro­borate anion, the B and F atoms are disordered over two sets of sites with site-occupancy factors of 0.813 (7) and 0.187 (7).
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spelling pubmed-34702192012-11-02 1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate Junge, Denise M. Scadova, Derek R. Golen, James A. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(13)H(19)N(2) (+)·BF(4) (−), an ionic liquid, the butyl and ethyl substituents bonded to the N atoms of the imidazole ring [r.m.s. deviation = 0.019 (1) Å] adopt equatorial positions. The crystal structure exhibits slipped π–π inter­actions between the imidazole and benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.529 (2) Å]. In the tetra­fluoro­borate anion, the B and F atoms are disordered over two sets of sites with site-occupancy factors of 0.813 (7) and 0.187 (7). International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470219/ /pubmed/23125663 http://dx.doi.org/10.1107/S1600536812037476 Text en © Junge et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Junge, Denise M.
Scadova, Derek R.
Golen, James A.
Jasinski, Jerry P.
1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate
title 1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate
title_full 1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate
title_fullStr 1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate
title_full_unstemmed 1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate
title_short 1-Butyl-3-ethyl-1H-benzimidazol-3-ium tetra­fluoro­borate
title_sort 1-butyl-3-ethyl-1h-benzimidazol-3-ium tetra­fluoro­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470219/
https://www.ncbi.nlm.nih.gov/pubmed/23125663
http://dx.doi.org/10.1107/S1600536812037476
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AT jasinskijerryp 1butyl3ethyl1hbenzimidazol3iumtetrafluoroborate

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