1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone

The title compound, C(29)H(26)O(4), is essentially planar in the acetophenone portion that includes both the hy­droxy and a benz­yloxy O atoms, with an r.m.s. deviation of 0.0311 Å. The other two substituents inter­sect the plane at 70.45 (3) and 59.55 (4)°. In the molecule there is an intramolecula...

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Detalles Bibliográficos
Autores principales: Hill, Tania N., Kuo, C.-M., Bezuidenhoudt, Barend C. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470220/
https://www.ncbi.nlm.nih.gov/pubmed/23125664
http://dx.doi.org/10.1107/S160053681203588X
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author Hill, Tania N.
Kuo, C.-M.
Bezuidenhoudt, Barend C. B.
author_facet Hill, Tania N.
Kuo, C.-M.
Bezuidenhoudt, Barend C. B.
author_sort Hill, Tania N.
collection PubMed
description The title compound, C(29)H(26)O(4), is essentially planar in the acetophenone portion that includes both the hy­droxy and a benz­yloxy O atoms, with an r.m.s. deviation of 0.0311 Å. The other two substituents inter­sect the plane at 70.45 (3) and 59.55 (4)°. In the molecule there is an intramolecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, as well as C—H⋯π and π-stacking inter­actions, with centroid–centroid distances 3.6570 (2) Å.
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spelling pubmed-34702202012-11-02 1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone Hill, Tania N. Kuo, C.-M. Bezuidenhoudt, Barend C. B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(29)H(26)O(4), is essentially planar in the acetophenone portion that includes both the hy­droxy and a benz­yloxy O atoms, with an r.m.s. deviation of 0.0311 Å. The other two substituents inter­sect the plane at 70.45 (3) and 59.55 (4)°. In the molecule there is an intramolecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, as well as C—H⋯π and π-stacking inter­actions, with centroid–centroid distances 3.6570 (2) Å. International Union of Crystallography 2012-09-05 /pmc/articles/PMC3470220/ /pubmed/23125664 http://dx.doi.org/10.1107/S160053681203588X Text en © Hill et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hill, Tania N.
Kuo, C.-M.
Bezuidenhoudt, Barend C. B.
1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone
title 1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone
title_full 1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone
title_fullStr 1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone
title_full_unstemmed 1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone
title_short 1-(3-Benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone
title_sort 1-(3-benzyl-4,6-dibenz­yloxy-2-hy­droxy­phen­yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470220/
https://www.ncbi.nlm.nih.gov/pubmed/23125664
http://dx.doi.org/10.1107/S160053681203588X
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