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2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)

In the title compound, C(24)H(29)BrO(6), the dihedral angle between the cyclo­hexenone mean planes is 57.63 (2)° while the dihedral angles between the benzene ring and the cyclo­hexenone mean planes are 58.42 (2) and 69.08 (3)°. The two cyclo­hexenone rings both show an envelope conformation, with t...

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Detalles Bibliográficos
Autores principales: Sughanya, V., Sureshbabu, N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470230/
https://www.ncbi.nlm.nih.gov/pubmed/23125674
http://dx.doi.org/10.1107/S1600536812037853
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author Sughanya, V.
Sureshbabu, N.
author_facet Sughanya, V.
Sureshbabu, N.
author_sort Sughanya, V.
collection PubMed
description In the title compound, C(24)H(29)BrO(6), the dihedral angle between the cyclo­hexenone mean planes is 57.63 (2)° while the dihedral angles between the benzene ring and the cyclo­hexenone mean planes are 58.42 (2) and 69.08 (3)°. The two cyclo­hexenone rings both show an envelope conformation, with the C atom bearing two methyl groups as the flap atom in each ring. Two intra­molecular O—H⋯O hydrogen bonds occur. In the crystal, molecules are linked via pairs of O—H⋯O hydrogen bonds, forming inversion dimers.
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spelling pubmed-34702302012-11-02 2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one) Sughanya, V. Sureshbabu, N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(29)BrO(6), the dihedral angle between the cyclo­hexenone mean planes is 57.63 (2)° while the dihedral angles between the benzene ring and the cyclo­hexenone mean planes are 58.42 (2) and 69.08 (3)°. The two cyclo­hexenone rings both show an envelope conformation, with the C atom bearing two methyl groups as the flap atom in each ring. Two intra­molecular O—H⋯O hydrogen bonds occur. In the crystal, molecules are linked via pairs of O—H⋯O hydrogen bonds, forming inversion dimers. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470230/ /pubmed/23125674 http://dx.doi.org/10.1107/S1600536812037853 Text en © Sughanya and Sureshbabu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sughanya, V.
Sureshbabu, N.
2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title 2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_full 2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_fullStr 2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_full_unstemmed 2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_short 2,2′-[(3-Bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
title_sort 2,2′-[(3-bromo-4-hy­droxy-5-meth­oxy­phen­yl)methyl­idene]bis­(3-hy­droxy-5,5-dimethyl­cyclo­hex-2-en-1-one)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470230/
https://www.ncbi.nlm.nih.gov/pubmed/23125674
http://dx.doi.org/10.1107/S1600536812037853
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AT sureshbabun 223bromo4hydroxy5methoxyphenylmethylidenebis3hydroxy55dimethylcyclohex2en1one