Cargando…

1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea

In the title compound, C(16)H(12)N(2)OS(2), the dihedral angles between the mean planes of the central thio­urea core and the thio­phene ring and the naphthalene ring system are 1.8 (2) and 6.45 (18)°, respectively. The mol­ecule adopts a trans–cis conformation with respect to the position of thio­p...

Descripción completa

Detalles Bibliográficos
Autores principales: Singh, Durga P., Pratap, Seema, Gupta, Sushil K., Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470236/
https://www.ncbi.nlm.nih.gov/pubmed/23125680
http://dx.doi.org/10.1107/S1600536812035350
_version_ 1782246226649939968
author Singh, Durga P.
Pratap, Seema
Gupta, Sushil K.
Butcher, Ray J.
author_facet Singh, Durga P.
Pratap, Seema
Gupta, Sushil K.
Butcher, Ray J.
author_sort Singh, Durga P.
collection PubMed
description In the title compound, C(16)H(12)N(2)OS(2), the dihedral angles between the mean planes of the central thio­urea core and the thio­phene ring and the naphthalene ring system are 1.8 (2) and 6.45 (18)°, respectively. The mol­ecule adopts a trans–cis conformation with respect to the position of thio­phenoyl and naphthyl groups relative to the S atom across the thiourea C—N bonds. Both the thio­phene ring and the sulfanyl­idene S atom are disordered over two sets of sites with occupancies of 0.862 (3):0.138 (3) and 0.977 (3):0.023 (3), respectively. An intra­molecular N—H⋯O hydrogen bond is observed. The crystal packing features two N—H⋯S hydrogen bonds.
format Online
Article
Text
id pubmed-3470236
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34702362012-11-02 1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea Singh, Durga P. Pratap, Seema Gupta, Sushil K. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(12)N(2)OS(2), the dihedral angles between the mean planes of the central thio­urea core and the thio­phene ring and the naphthalene ring system are 1.8 (2) and 6.45 (18)°, respectively. The mol­ecule adopts a trans–cis conformation with respect to the position of thio­phenoyl and naphthyl groups relative to the S atom across the thiourea C—N bonds. Both the thio­phene ring and the sulfanyl­idene S atom are disordered over two sets of sites with occupancies of 0.862 (3):0.138 (3) and 0.977 (3):0.023 (3), respectively. An intra­molecular N—H⋯O hydrogen bond is observed. The crystal packing features two N—H⋯S hydrogen bonds. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470236/ /pubmed/23125680 http://dx.doi.org/10.1107/S1600536812035350 Text en © Singh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Singh, Durga P.
Pratap, Seema
Gupta, Sushil K.
Butcher, Ray J.
1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea
title 1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea
title_full 1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea
title_fullStr 1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea
title_full_unstemmed 1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea
title_short 1-(Naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea
title_sort 1-(naphthalen-1-yl)-3-[(thio­phen-2-yl)carbon­yl]thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470236/
https://www.ncbi.nlm.nih.gov/pubmed/23125680
http://dx.doi.org/10.1107/S1600536812035350
work_keys_str_mv AT singhdurgap 1naphthalen1yl3thiophen2ylcarbonylthiourea
AT pratapseema 1naphthalen1yl3thiophen2ylcarbonylthiourea
AT guptasushilk 1naphthalen1yl3thiophen2ylcarbonylthiourea
AT butcherrayj 1naphthalen1yl3thiophen2ylcarbonylthiourea