4-Cyano­anilinium bromide

In the crystal structure of the title compound, C(7)H(7)N(2) (+)·Br(−), the cations are associated into inversion dimers through weak pairwise C—H⋯N hydrogen bonds. The dimers further form stepped sheets via weak pairwise C—H⋯N hydrogen bonds. In the sheets, the spacing between the mean planes of th...

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Detalles Bibliográficos
Autores principales: Vumbaco, David J., Kammer, Michael N., Koplitz, Lynn V., Mague, Joel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470237/
https://www.ncbi.nlm.nih.gov/pubmed/23125681
http://dx.doi.org/10.1107/S1600536812037014
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author Vumbaco, David J.
Kammer, Michael N.
Koplitz, Lynn V.
Mague, Joel T.
author_facet Vumbaco, David J.
Kammer, Michael N.
Koplitz, Lynn V.
Mague, Joel T.
author_sort Vumbaco, David J.
collection PubMed
description In the crystal structure of the title compound, C(7)H(7)N(2) (+)·Br(−), the cations are associated into inversion dimers through weak pairwise C—H⋯N hydrogen bonds. The dimers further form stepped sheets via weak pairwise C—H⋯N hydrogen bonds. In the sheets, the spacing between the mean planes of the laterally displaced aromatic rings in adjacent dimers is 1.124 (6) Å. Three N—H⋯Br inter­actions and two weak C—H⋯Br inter­actions per cation tie the sheets together.
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spelling pubmed-34702372012-11-02 4-Cyano­anilinium bromide Vumbaco, David J. Kammer, Michael N. Koplitz, Lynn V. Mague, Joel T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(7)H(7)N(2) (+)·Br(−), the cations are associated into inversion dimers through weak pairwise C—H⋯N hydrogen bonds. The dimers further form stepped sheets via weak pairwise C—H⋯N hydrogen bonds. In the sheets, the spacing between the mean planes of the laterally displaced aromatic rings in adjacent dimers is 1.124 (6) Å. Three N—H⋯Br inter­actions and two weak C—H⋯Br inter­actions per cation tie the sheets together. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470237/ /pubmed/23125681 http://dx.doi.org/10.1107/S1600536812037014 Text en © Vumbaco et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vumbaco, David J.
Kammer, Michael N.
Koplitz, Lynn V.
Mague, Joel T.
4-Cyano­anilinium bromide
title 4-Cyano­anilinium bromide
title_full 4-Cyano­anilinium bromide
title_fullStr 4-Cyano­anilinium bromide
title_full_unstemmed 4-Cyano­anilinium bromide
title_short 4-Cyano­anilinium bromide
title_sort 4-cyano­anilinium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470237/
https://www.ncbi.nlm.nih.gov/pubmed/23125681
http://dx.doi.org/10.1107/S1600536812037014
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