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3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1)

The title two-component mol­ecular crystal, C(10)H(8)N(2)·C(2)H(4)N(4)S, was obtained unexpectedly by reaction of Zn(NO(3))(2)·6H(2)O, NH(4)BF(4) with 3-amino-1,2,4-triazole-5-thione (3-AMT) and 4,4′-bipyridine in water. The dihedral angle between the pyridine rings in the 4,4′-bipyridine molecule i...

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Autores principales: Qiu, Qi-Ming, Jiang, Yu-Han, Huang, Xu, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470238/
https://www.ncbi.nlm.nih.gov/pubmed/23125682
http://dx.doi.org/10.1107/S1600536812037671
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author Qiu, Qi-Ming
Jiang, Yu-Han
Huang, Xu
Jin, Qiong-Hua
Zhang, Cun-Lin
author_facet Qiu, Qi-Ming
Jiang, Yu-Han
Huang, Xu
Jin, Qiong-Hua
Zhang, Cun-Lin
author_sort Qiu, Qi-Ming
collection PubMed
description The title two-component mol­ecular crystal, C(10)H(8)N(2)·C(2)H(4)N(4)S, was obtained unexpectedly by reaction of Zn(NO(3))(2)·6H(2)O, NH(4)BF(4) with 3-amino-1,2,4-triazole-5-thione (3-AMT) and 4,4′-bipyridine in water. The dihedral angle between the pyridine rings in the 4,4′-bipyridine molecule is 17.00 (13)°. In the crystal, N—H⋯N and N—H⋯S hydrogen bonds between the components lead to the formation of a three-dimensional network. Furthermore, the structure features face-to-face π–π stacking inter­actions between the 4,4′-bipyridine and triazole rings, with a centroid–centroid distance of 2.976 (2) Å.
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spelling pubmed-34702382012-11-02 3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1) Qiu, Qi-Ming Jiang, Yu-Han Huang, Xu Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title two-component mol­ecular crystal, C(10)H(8)N(2)·C(2)H(4)N(4)S, was obtained unexpectedly by reaction of Zn(NO(3))(2)·6H(2)O, NH(4)BF(4) with 3-amino-1,2,4-triazole-5-thione (3-AMT) and 4,4′-bipyridine in water. The dihedral angle between the pyridine rings in the 4,4′-bipyridine molecule is 17.00 (13)°. In the crystal, N—H⋯N and N—H⋯S hydrogen bonds between the components lead to the formation of a three-dimensional network. Furthermore, the structure features face-to-face π–π stacking inter­actions between the 4,4′-bipyridine and triazole rings, with a centroid–centroid distance of 2.976 (2) Å. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470238/ /pubmed/23125682 http://dx.doi.org/10.1107/S1600536812037671 Text en © Qiu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qiu, Qi-Ming
Jiang, Yu-Han
Huang, Xu
Jin, Qiong-Hua
Zhang, Cun-Lin
3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1)
title 3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1)
title_full 3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1)
title_fullStr 3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1)
title_full_unstemmed 3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1)
title_short 3-Amino-1H-1,2,4-triazole-5(4H)-thione–4,4′-bipyridine (1/1)
title_sort 3-amino-1h-1,2,4-triazole-5(4h)-thione–4,4′-bipyridine (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470238/
https://www.ncbi.nlm.nih.gov/pubmed/23125682
http://dx.doi.org/10.1107/S1600536812037671
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