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4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile
The asymmetric unit of the title Schiff base, C(14)H(11)N(3)O, contains two independent molecules which have similar conformations. The dihedral angles between the benzene rings are 4.19 (9) and 14.18 (9)° in the two molecules. An intramolecular O—H⋯N hydrogen bond stabilizes the molecular confo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470239/ https://www.ncbi.nlm.nih.gov/pubmed/23125683 http://dx.doi.org/10.1107/S1600536812037841 |
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author | Mohamed, Shaaban K. Bogdanović, Goran A. Abdelhamid, Antar A. Novaković, Sladjana B. Potgeiter, Herman |
author_facet | Mohamed, Shaaban K. Bogdanović, Goran A. Abdelhamid, Antar A. Novaković, Sladjana B. Potgeiter, Herman |
author_sort | Mohamed, Shaaban K. |
collection | PubMed |
description | The asymmetric unit of the title Schiff base, C(14)H(11)N(3)O, contains two independent molecules which have similar conformations. The dihedral angles between the benzene rings are 4.19 (9) and 14.18 (9)° in the two molecules. An intramolecular O—H⋯N hydrogen bond stabilizes the molecular conformation of each molecules. The crystal packing is dominated by pairs of equivalent N—H⋯N and C—H⋯O hydrogen bonds which arrange the molecules into layers parallel to (-111). |
format | Online Article Text |
id | pubmed-3470239 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34702392012-11-02 4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile Mohamed, Shaaban K. Bogdanović, Goran A. Abdelhamid, Antar A. Novaković, Sladjana B. Potgeiter, Herman Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title Schiff base, C(14)H(11)N(3)O, contains two independent molecules which have similar conformations. The dihedral angles between the benzene rings are 4.19 (9) and 14.18 (9)° in the two molecules. An intramolecular O—H⋯N hydrogen bond stabilizes the molecular conformation of each molecules. The crystal packing is dominated by pairs of equivalent N—H⋯N and C—H⋯O hydrogen bonds which arrange the molecules into layers parallel to (-111). International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470239/ /pubmed/23125683 http://dx.doi.org/10.1107/S1600536812037841 Text en © Mohamed et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mohamed, Shaaban K. Bogdanović, Goran A. Abdelhamid, Antar A. Novaković, Sladjana B. Potgeiter, Herman 4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile |
title | 4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile |
title_full | 4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile |
title_fullStr | 4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile |
title_full_unstemmed | 4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile |
title_short | 4-[(2E)-2-(2-Hydroxybenzylidene)hydrazin-1-yl]benzonitrile |
title_sort | 4-[(2e)-2-(2-hydroxybenzylidene)hydrazin-1-yl]benzonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470239/ https://www.ncbi.nlm.nih.gov/pubmed/23125683 http://dx.doi.org/10.1107/S1600536812037841 |
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