O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate

The P atom in the title compound, C(8)H(18)NO(2)PS, is bonded in a distorted tetra­hedral PSO(2)N environment with bond angles in the range of 99.23 (5)–115.17 (4)°. The cyclo­hexane ring is disordered over two sets of sites with refined occupancies of 0.528 (5) and 0.472 (5). The ring in both disor...

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Detalles Bibliográficos
Autores principales: Sabbaghi, Fahimeh, Pourayoubi, Mehrdad, Nečas, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470243/
https://www.ncbi.nlm.nih.gov/pubmed/23125687
http://dx.doi.org/10.1107/S160053681203766X
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author Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
author_facet Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
author_sort Sabbaghi, Fahimeh
collection PubMed
description The P atom in the title compound, C(8)H(18)NO(2)PS, is bonded in a distorted tetra­hedral PSO(2)N environment with bond angles in the range of 99.23 (5)–115.17 (4)°. The cyclo­hexane ring is disordered over two sets of sites with refined occupancies of 0.528 (5) and 0.472 (5). The ring in both disorder components adopts a chair conformation with the N—H group oriented equatorially. In the crystal, pairs of P=S⋯H—N hydrogen bonds form inversion dimers.
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spelling pubmed-34702432012-11-02 O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate Sabbaghi, Fahimeh Pourayoubi, Mehrdad Nečas, Marek Acta Crystallogr Sect E Struct Rep Online Organic Papers The P atom in the title compound, C(8)H(18)NO(2)PS, is bonded in a distorted tetra­hedral PSO(2)N environment with bond angles in the range of 99.23 (5)–115.17 (4)°. The cyclo­hexane ring is disordered over two sets of sites with refined occupancies of 0.528 (5) and 0.472 (5). The ring in both disorder components adopts a chair conformation with the N—H group oriented equatorially. In the crystal, pairs of P=S⋯H—N hydrogen bonds form inversion dimers. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470243/ /pubmed/23125687 http://dx.doi.org/10.1107/S160053681203766X Text en © Sabbaghi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate
title O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate
title_full O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate
title_fullStr O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate
title_full_unstemmed O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate
title_short O,O′-Dimethyl (cyclo­hexyl­amido)­thio­phosphate
title_sort o,o′-dimethyl (cyclo­hexyl­amido)­thio­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470243/
https://www.ncbi.nlm.nih.gov/pubmed/23125687
http://dx.doi.org/10.1107/S160053681203766X
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AT pourayoubimehrdad oodimethylcyclohexylamidothiophosphate
AT necasmarek oodimethylcyclohexylamidothiophosphate

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