Cargando…

3,5,3′,5′-Tetra­methyl-4,4′-bi(1H-pyrazol­yl) hemihydrate

In the title compound, C(10)H(14)N(4)·0.5H(2)O, the amino H atom of one of the two pyrazole rings is disordered over its two N atoms in a 1:1 ratio. The pyrazole rings are aligned at 60.1 (1)°. In the crystal, two bipyrazolyl mol­ecules are linked by an N—H⋯N hydrogen bond, generating a dimer; the d...

Descripción completa

Detalles Bibliográficos
Autores principales: Jin, Shouwen, Huang, Yanfei, Fang, Hao, Wang, Tianyi, Ding, Liangliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470248/
https://www.ncbi.nlm.nih.gov/pubmed/23125692
http://dx.doi.org/10.1107/S1600536812037920
Descripción
Sumario:In the title compound, C(10)H(14)N(4)·0.5H(2)O, the amino H atom of one of the two pyrazole rings is disordered over its two N atoms in a 1:1 ratio. The pyrazole rings are aligned at 60.1 (1)°. In the crystal, two bipyrazolyl mol­ecules are linked by an N—H⋯N hydrogen bond, generating a dimer; the dimer is connected to the water mol­ecule, which lies on a twofold rotation axis, resulting in the formation of a chain that makes an angle of ca 45.3 (1)° with the ab plane. The chains are cross-linked by N—H⋯O and O—H⋯N inter­actions, forming a three-dimensional network.