Cargando…
5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione
In the title compound, C(37)H(30)Cl(4)N(2)O(2), the pyridinone ring adopts a twisted half-chair conformation. In the octahydroindolizine fused-ring system, the piperidine ring is in a chair conformation and the pyrrole ring is twisted about the C—N bond linking the five- and six-membered rings. Th...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470255/ https://www.ncbi.nlm.nih.gov/pubmed/23125699 http://dx.doi.org/10.1107/S1600536812037956 |
| _version_ | 1782246231030890496 |
|---|---|
| author | Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha |
| author_facet | Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha |
| author_sort | Suresh, J. |
| collection | PubMed |
| description | In the title compound, C(37)H(30)Cl(4)N(2)O(2), the pyridinone ring adopts a twisted half-chair conformation. In the octahydroindolizine fused-ring system, the piperidine ring is in a chair conformation and the pyrrole ring is twisted about the C—N bond linking the five- and six-membered rings. The molecular structure features an intramolecular C—H⋯O interaction and the crystal packing is stabilized by C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3470255 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34702552012-11-02 5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(37)H(30)Cl(4)N(2)O(2), the pyridinone ring adopts a twisted half-chair conformation. In the octahydroindolizine fused-ring system, the piperidine ring is in a chair conformation and the pyrrole ring is twisted about the C—N bond linking the five- and six-membered rings. The molecular structure features an intramolecular C—H⋯O interaction and the crystal packing is stabilized by C—H⋯π interactions. International Union of Crystallography 2012-09-08 /pmc/articles/PMC3470255/ /pubmed/23125699 http://dx.doi.org/10.1107/S1600536812037956 Text en © Suresh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Suresh, J. Vishnupriya, R. Kumar, R. Ranjith Sivakumar, S. Lakshman, P. L. Nilantha 5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione |
| title | 5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione |
| title_full | 5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione |
| title_fullStr | 5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione |
| title_full_unstemmed | 5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione |
| title_short | 5′′-(2,4-Dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1H)-dione |
| title_sort | 5′′-(2,4-dichlorobenzylidene)-1′-(2,4-dichlorophenyl)-1′′-methyl-1′,2′,3′,5′,6′,7′,8′,8a’-octahydrodispiro[acenaphthylene-1,3′-indolizine-2′,3′′-piperidine]-2,4′′(1h)-dione |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470255/ https://www.ncbi.nlm.nih.gov/pubmed/23125699 http://dx.doi.org/10.1107/S1600536812037956 |
| work_keys_str_mv | AT sureshj 524dichlorobenzylidene124dichlorophenyl1methyl12356788aoctahydrodispiroacenaphthylene13indolizine23piperidine241hdione AT vishnupriyar 524dichlorobenzylidene124dichlorophenyl1methyl12356788aoctahydrodispiroacenaphthylene13indolizine23piperidine241hdione AT kumarrranjith 524dichlorobenzylidene124dichlorophenyl1methyl12356788aoctahydrodispiroacenaphthylene13indolizine23piperidine241hdione AT sivakumars 524dichlorobenzylidene124dichlorophenyl1methyl12356788aoctahydrodispiroacenaphthylene13indolizine23piperidine241hdione AT lakshmanplnilantha 524dichlorobenzylidene124dichlorophenyl1methyl12356788aoctahydrodispiroacenaphthylene13indolizine23piperidine241hdione |