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2,9,12,15,18,25,27,34,37,40,43,50-Dodecaoxa-56-azaheptacyclo[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexapentaconta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-pentadecaene
The title compound, C(43)H(45)NO(12), was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal,...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470260/ https://www.ncbi.nlm.nih.gov/pubmed/23125704 http://dx.doi.org/10.1107/S1600536812038093 |
| Sumario: | The title compound, C(43)H(45)NO(12), was prepared from the reaction of 2,6-bis(dibromomethyl)pyridine and bisphenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal, molecules are linked by weak C—H⋯O and C—H⋯π interactions, forming a folded structure. |
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