2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene

The title compound, C(43)H(45)NO(12), was prepared from the reaction of 2,6-bis­(dibromo­meth­yl)pyridine and bis­phenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal,...

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Detalles Bibliográficos
Autores principales: Kim, Jun Hee, Yoon, Il, Sim, Wonbo, Lee, Jai Young
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470260/
https://www.ncbi.nlm.nih.gov/pubmed/23125704
http://dx.doi.org/10.1107/S1600536812038093
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author Kim, Jun Hee
Yoon, Il
Sim, Wonbo
Lee, Jai Young
author_facet Kim, Jun Hee
Yoon, Il
Sim, Wonbo
Lee, Jai Young
author_sort Kim, Jun Hee
collection PubMed
description The title compound, C(43)H(45)NO(12), was prepared from the reaction of 2,6-bis­(dibromo­meth­yl)pyridine and bis­phenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π inter­actions, forming a folded structure.
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spelling pubmed-34702602012-11-02 2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene Kim, Jun Hee Yoon, Il Sim, Wonbo Lee, Jai Young Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(43)H(45)NO(12), was prepared from the reaction of 2,6-bis­(dibromo­meth­yl)pyridine and bis­phenol in the presence of caesium carbonate as a base. The central ring makes dihedral angles of 64.83 (6), 13.48 (6), 56.96 (6) and 66.21 (6)° with the peripheral rings. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯π inter­actions, forming a folded structure. International Union of Crystallography 2012-09-12 /pmc/articles/PMC3470260/ /pubmed/23125704 http://dx.doi.org/10.1107/S1600536812038093 Text en © Kim et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kim, Jun Hee
Yoon, Il
Sim, Wonbo
Lee, Jai Young
2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene
title 2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene
title_full 2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene
title_fullStr 2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene
title_full_unstemmed 2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene
title_short 2,9,12,15,18,25,27,34,37,40,43,50-Dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene
title_sort 2,9,12,15,18,25,27,34,37,40,43,50-dodeca­oxa-56-aza­hepta­cyclo­[24.24.5.1(51,55).0(3,8).0(19,24).0(28,33).0(44,49)]hexa­penta­conta-3,5,7,19(24),20,22,28(33),29,31,44,46,48,51,53,55-penta­deca­ene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470260/
https://www.ncbi.nlm.nih.gov/pubmed/23125704
http://dx.doi.org/10.1107/S1600536812038093
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