N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide

In the title compound, C(18)H(18)ClN(5)O(3), the hydrazinecarboxamide N—N—C(O)—N unit is nearly planar [maximum deviation = 0.074 (2) Å] and is inclined at a dihedral angle of 57.43 (7)° with respect to the plane of the attached benzene ring. The chloro­phenyl group makes dihedral angles of 19.71 (7...

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Autores principales: Kant, Rajni, Gupta, Vivek K., Kapoor, Kamini, Shripanavar, Chetan S., Banerjee, Kaushik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470263/
https://www.ncbi.nlm.nih.gov/pubmed/23125707
http://dx.doi.org/10.1107/S1600536812038214
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author Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
author_facet Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
author_sort Kant, Rajni
collection PubMed
description In the title compound, C(18)H(18)ClN(5)O(3), the hydrazinecarboxamide N—N—C(O)—N unit is nearly planar [maximum deviation = 0.074 (2) Å] and is inclined at a dihedral angle of 57.43 (7)° with respect to the plane of the attached benzene ring. The chloro­phenyl group makes dihedral angles of 19.71 (7) and 34.07 (6)° with the pyrazole and benzene rings, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers that are further linked into chains along the a-axis direction by N—H⋯N hydrogen bonds. In addition, π–π stacking inter­actions are observed between benzene rings [centroid–centroid distance = 3.680 (1) Å].
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spelling pubmed-34702632012-11-02 N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Shripanavar, Chetan S. Banerjee, Kaushik Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(18)ClN(5)O(3), the hydrazinecarboxamide N—N—C(O)—N unit is nearly planar [maximum deviation = 0.074 (2) Å] and is inclined at a dihedral angle of 57.43 (7)° with respect to the plane of the attached benzene ring. The chloro­phenyl group makes dihedral angles of 19.71 (7) and 34.07 (6)° with the pyrazole and benzene rings, respectively. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into inversion dimers that are further linked into chains along the a-axis direction by N—H⋯N hydrogen bonds. In addition, π–π stacking inter­actions are observed between benzene rings [centroid–centroid distance = 3.680 (1) Å]. International Union of Crystallography 2012-09-12 /pmc/articles/PMC3470263/ /pubmed/23125707 http://dx.doi.org/10.1107/S1600536812038214 Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide
title N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide
title_full N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide
title_fullStr N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide
title_full_unstemmed N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide
title_short N-[2-({[1-(4-Chloro­phen­yl)-1H-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-N-meth­oxy­hydrazinecarboxamide
title_sort n-[2-({[1-(4-chloro­phen­yl)-1h-pyrazol-3-yl]­oxy}meth­yl)phen­yl]-n-meth­oxy­hydrazinecarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470263/
https://www.ncbi.nlm.nih.gov/pubmed/23125707
http://dx.doi.org/10.1107/S1600536812038214
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AT shripanavarchetans n214chlorophenyl1hpyrazol3yloxymethylphenylnmethoxyhydrazinecarboxamide
AT banerjeekaushik n214chlorophenyl1hpyrazol3yloxymethylphenylnmethoxyhydrazinecarboxamide

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