1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate

In the title compound, C(35)H(28)O(6)·C(7)H(8), the dihedral angle between the mean planes through the naphthalene ring systems of the dibenzo[a,g]fluorene moiety is 22.44 (3)°. The aromatic ring system of the naphthalenone unit is approximately perpendicular to the mean plane of the five-membered r...

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Detalles Bibliográficos
Autores principales: Takeuchi, Ryo, Nagasawa, Atsushi, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470265/
https://www.ncbi.nlm.nih.gov/pubmed/23125709
http://dx.doi.org/10.1107/S160053681203824X
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author Takeuchi, Ryo
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Takeuchi, Ryo
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Takeuchi, Ryo
collection PubMed
description In the title compound, C(35)H(28)O(6)·C(7)H(8), the dihedral angle between the mean planes through the naphthalene ring systems of the dibenzo[a,g]fluorene moiety is 22.44 (3)°. The aromatic ring system of the naphthalenone unit is approximately perpendicular to the mean plane of the five-membered ring, forming a dihedral angle of 87.51 (5)°. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal, pairs of C—H⋯π inter­actions link the mol­ecules, forming inversion dimers.
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spelling pubmed-34702652012-11-02 1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate Takeuchi, Ryo Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(28)O(6)·C(7)H(8), the dihedral angle between the mean planes through the naphthalene ring systems of the dibenzo[a,g]fluorene moiety is 22.44 (3)°. The aromatic ring system of the naphthalenone unit is approximately perpendicular to the mean plane of the five-membered ring, forming a dihedral angle of 87.51 (5)°. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal, pairs of C—H⋯π inter­actions link the mol­ecules, forming inversion dimers. International Union of Crystallography 2012-09-12 /pmc/articles/PMC3470265/ /pubmed/23125709 http://dx.doi.org/10.1107/S160053681203824X Text en © Takeuchi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Takeuchi, Ryo
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate
title 1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate
title_full 1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate
title_fullStr 1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate
title_full_unstemmed 1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate
title_short 1,5,7,8′,11-Penta­meth­oxy-13H-spiro­[dibenzo[a,g]fluorene-13,1′(4′H)-naphthalen]-4′-one toluene monosolvate
title_sort 1,5,7,8′,11-penta­meth­oxy-13h-spiro­[dibenzo[a,g]fluorene-13,1′(4′h)-naphthalen]-4′-one toluene monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470265/
https://www.ncbi.nlm.nih.gov/pubmed/23125709
http://dx.doi.org/10.1107/S160053681203824X
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