Diphenyl (methyl­amido)­phosphate

The N—H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra­hedral coordination; its bond angles are in the range 93.96 (5)–116.83 (6)°. In the c...

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Detalles Bibliográficos
Autores principales: Sabbaghi, Fahimeh, Pourayoubi, Mehrdad, Nečas, Marek, Bartoš, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470308/
https://www.ncbi.nlm.nih.gov/pubmed/23125721
http://dx.doi.org/10.1107/S160053681203869X
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author Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
Bartoš, Peter
author_facet Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
Bartoš, Peter
author_sort Sabbaghi, Fahimeh
collection PubMed
description The N—H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra­hedral coordination; its bond angles are in the range 93.96 (5)–116.83 (6)°. In the crystal, mol­ecules form centrosymmetric dimers through P=O⋯H—N hydrogen bonds.
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spelling pubmed-34703082012-11-02 Diphenyl (methyl­amido)­phosphate Sabbaghi, Fahimeh Pourayoubi, Mehrdad Nečas, Marek Bartoš, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers The N—H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra­hedral coordination; its bond angles are in the range 93.96 (5)–116.83 (6)°. In the crystal, mol­ecules form centrosymmetric dimers through P=O⋯H—N hydrogen bonds. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470308/ /pubmed/23125721 http://dx.doi.org/10.1107/S160053681203869X Text en © Sabbaghi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Nečas, Marek
Bartoš, Peter
Diphenyl (methyl­amido)­phosphate
title Diphenyl (methyl­amido)­phosphate
title_full Diphenyl (methyl­amido)­phosphate
title_fullStr Diphenyl (methyl­amido)­phosphate
title_full_unstemmed Diphenyl (methyl­amido)­phosphate
title_short Diphenyl (methyl­amido)­phosphate
title_sort diphenyl (methyl­amido)­phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470308/
https://www.ncbi.nlm.nih.gov/pubmed/23125721
http://dx.doi.org/10.1107/S160053681203869X
work_keys_str_mv AT sabbaghifahimeh diphenylmethylamidophosphate
AT pourayoubimehrdad diphenylmethylamidophosphate
AT necasmarek diphenylmethylamidophosphate
AT bartospeter diphenylmethylamidophosphate

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