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Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)

The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine mol­ecule and one-half mol­ecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent be...

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Autores principales: Thanigaimani, Kaliyaperumal, Razak, Ibrahim Abdul, Arshad, Suhana, Jagatheesan, Rathinavel, Santhanaraj, Kulandaisamy Joseph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470311/
https://www.ncbi.nlm.nih.gov/pubmed/23125724
http://dx.doi.org/10.1107/S1600536812038743
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author Thanigaimani, Kaliyaperumal
Razak, Ibrahim Abdul
Arshad, Suhana
Jagatheesan, Rathinavel
Santhanaraj, Kulandaisamy Joseph
author_facet Thanigaimani, Kaliyaperumal
Razak, Ibrahim Abdul
Arshad, Suhana
Jagatheesan, Rathinavel
Santhanaraj, Kulandaisamy Joseph
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine mol­ecule and one-half mol­ecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent benzene ring. In the crystal, the components are linked by N—H⋯O and O—H⋯N hydrogen bonds, thus generating a centrosymmetric 2 + 1 unit of triazine and adipic acid mol­ecules with R (2) (2)(8) motifs. The triazine mol­ecules are connected to each other by N—H⋯N hydrogen bonds, forming an R (2) (2)(8) motif and a supra­molecular ribbon along the c axis. The 2 + 1 units and the supra­molecular ribbons are further inter­linked by weak N—H⋯O, C—H⋯O and C—H⋯π inter­actions, resulting in a three-dimensional network.
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spelling pubmed-34703112012-11-02 Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2) Thanigaimani, Kaliyaperumal Razak, Ibrahim Abdul Arshad, Suhana Jagatheesan, Rathinavel Santhanaraj, Kulandaisamy Joseph Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine mol­ecule and one-half mol­ecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent benzene ring. In the crystal, the components are linked by N—H⋯O and O—H⋯N hydrogen bonds, thus generating a centrosymmetric 2 + 1 unit of triazine and adipic acid mol­ecules with R (2) (2)(8) motifs. The triazine mol­ecules are connected to each other by N—H⋯N hydrogen bonds, forming an R (2) (2)(8) motif and a supra­molecular ribbon along the c axis. The 2 + 1 units and the supra­molecular ribbons are further inter­linked by weak N—H⋯O, C—H⋯O and C—H⋯π inter­actions, resulting in a three-dimensional network. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470311/ /pubmed/23125724 http://dx.doi.org/10.1107/S1600536812038743 Text en © Thanigaimani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Razak, Ibrahim Abdul
Arshad, Suhana
Jagatheesan, Rathinavel
Santhanaraj, Kulandaisamy Joseph
Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)
title Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)
title_full Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)
title_fullStr Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)
title_full_unstemmed Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)
title_short Adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)
title_sort adipic acid–2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine (1/2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470311/
https://www.ncbi.nlm.nih.gov/pubmed/23125724
http://dx.doi.org/10.1107/S1600536812038743
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