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Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2)
The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine molecule and one-half molecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent be...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470311/ https://www.ncbi.nlm.nih.gov/pubmed/23125724 http://dx.doi.org/10.1107/S1600536812038743 |
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author | Thanigaimani, Kaliyaperumal Razak, Ibrahim Abdul Arshad, Suhana Jagatheesan, Rathinavel Santhanaraj, Kulandaisamy Joseph |
author_facet | Thanigaimani, Kaliyaperumal Razak, Ibrahim Abdul Arshad, Suhana Jagatheesan, Rathinavel Santhanaraj, Kulandaisamy Joseph |
author_sort | Thanigaimani, Kaliyaperumal |
collection | PubMed |
description | The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine molecule and one-half molecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent benzene ring. In the crystal, the components are linked by N—H⋯O and O—H⋯N hydrogen bonds, thus generating a centrosymmetric 2 + 1 unit of triazine and adipic acid molecules with R (2) (2)(8) motifs. The triazine molecules are connected to each other by N—H⋯N hydrogen bonds, forming an R (2) (2)(8) motif and a supramolecular ribbon along the c axis. The 2 + 1 units and the supramolecular ribbons are further interlinked by weak N—H⋯O, C—H⋯O and C—H⋯π interactions, resulting in a three-dimensional network. |
format | Online Article Text |
id | pubmed-3470311 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34703112012-11-02 Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) Thanigaimani, Kaliyaperumal Razak, Ibrahim Abdul Arshad, Suhana Jagatheesan, Rathinavel Santhanaraj, Kulandaisamy Joseph Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine molecule and one-half molecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent benzene ring. In the crystal, the components are linked by N—H⋯O and O—H⋯N hydrogen bonds, thus generating a centrosymmetric 2 + 1 unit of triazine and adipic acid molecules with R (2) (2)(8) motifs. The triazine molecules are connected to each other by N—H⋯N hydrogen bonds, forming an R (2) (2)(8) motif and a supramolecular ribbon along the c axis. The 2 + 1 units and the supramolecular ribbons are further interlinked by weak N—H⋯O, C—H⋯O and C—H⋯π interactions, resulting in a three-dimensional network. International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470311/ /pubmed/23125724 http://dx.doi.org/10.1107/S1600536812038743 Text en © Thanigaimani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Thanigaimani, Kaliyaperumal Razak, Ibrahim Abdul Arshad, Suhana Jagatheesan, Rathinavel Santhanaraj, Kulandaisamy Joseph Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) |
title | Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) |
title_full | Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) |
title_fullStr | Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) |
title_full_unstemmed | Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) |
title_short | Adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) |
title_sort | adipic acid–2,4-diamino-6-(4-methoxyphenyl)-1,3,5-triazine (1/2) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470311/ https://www.ncbi.nlm.nih.gov/pubmed/23125724 http://dx.doi.org/10.1107/S1600536812038743 |
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