1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate

In the cation of the title hydrated salt, C(11)H(9)N(4)O(4) (+)·Cl(−)·H(2)O, the six-membered rings are inclined to each other at 79.0 (1)° and an intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯Cl hydrogen bonds link two cations and two anions into centrosymmetric group, and O—H⋯Cl...

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Detalles Bibliográficos
Autores principales: Babykala, Rajamanickam, Kalaivani, Doraisamyraja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470313/
https://www.ncbi.nlm.nih.gov/pubmed/23125726
http://dx.doi.org/10.1107/S1600536812038834
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author Babykala, Rajamanickam
Kalaivani, Doraisamyraja
author_facet Babykala, Rajamanickam
Kalaivani, Doraisamyraja
author_sort Babykala, Rajamanickam
collection PubMed
description In the cation of the title hydrated salt, C(11)H(9)N(4)O(4) (+)·Cl(−)·H(2)O, the six-membered rings are inclined to each other at 79.0 (1)° and an intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯Cl hydrogen bonds link two cations and two anions into centrosymmetric group, and O—H⋯Cl hydrogen bonds involving the water mol­ecules further link these groups into chains in [101]. An O—H⋯O inter­action is also present. The water mol­ecule is disordered over two sets of sites in a 0.555 (13):0.445 (13) ratio
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spelling pubmed-34703132012-11-02 1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate Babykala, Rajamanickam Kalaivani, Doraisamyraja Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title hydrated salt, C(11)H(9)N(4)O(4) (+)·Cl(−)·H(2)O, the six-membered rings are inclined to each other at 79.0 (1)° and an intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, N—H⋯Cl hydrogen bonds link two cations and two anions into centrosymmetric group, and O—H⋯Cl hydrogen bonds involving the water mol­ecules further link these groups into chains in [101]. An O—H⋯O inter­action is also present. The water mol­ecule is disordered over two sets of sites in a 0.555 (13):0.445 (13) ratio International Union of Crystallography 2012-09-15 /pmc/articles/PMC3470313/ /pubmed/23125726 http://dx.doi.org/10.1107/S1600536812038834 Text en © Babykala and Kalaivani 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Babykala, Rajamanickam
Kalaivani, Doraisamyraja
1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate
title 1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate
title_full 1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate
title_fullStr 1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate
title_full_unstemmed 1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate
title_short 1-(5-Amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate
title_sort 1-(5-amino-2,4-dinitro­phen­yl)pyridinium chloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470313/
https://www.ncbi.nlm.nih.gov/pubmed/23125726
http://dx.doi.org/10.1107/S1600536812038834
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AT kalaivanidoraisamyraja 15amino24dinitrophenylpyridiniumchloridemonohydrate

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