2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one

The title compound, C(25)H(29)Br(2)NO, is a tert-pentyl analog of 2,4-bis­(2-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Par­thiban et al. (2008 ▶). Acta Cryst. E64, o2385]. Similar to its analog, the title compound exists in a twin-chair conformation with an equatorial orientation of the 2-bro...

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Detalles Bibliográficos
Autores principales: Park, Dong Ho, Ramkumar, V., Parthiban, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470318/
https://www.ncbi.nlm.nih.gov/pubmed/23125731
http://dx.doi.org/10.1107/S1600536812039128
Descripción
Sumario:The title compound, C(25)H(29)Br(2)NO, is a tert-pentyl analog of 2,4-bis­(2-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Par­thiban et al. (2008 ▶). Acta Cryst. E64, o2385]. Similar to its analog, the title compound exists in a twin-chair conformation with an equatorial orientation of the 2-bromo­phenyl groups. The benzene rings are inclined to each other at a dihedral angle of 29.6 (3)°. The tert-pentyl group on the cyclo­hexa­none ring also adopts an exocyclic equatorial disposition.

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