2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one

The title compound, C(25)H(29)Br(2)NO, is a tert-pentyl analog of 2,4-bis­(2-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Par­thiban et al. (2008 ▶). Acta Cryst. E64, o2385]. Similar to its analog, the title compound exists in a twin-chair conformation with an equatorial orientation of the 2-bro...

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Detalles Bibliográficos
Autores principales: Park, Dong Ho, Ramkumar, V., Parthiban, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470318/
https://www.ncbi.nlm.nih.gov/pubmed/23125731
http://dx.doi.org/10.1107/S1600536812039128
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author Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_facet Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_sort Park, Dong Ho
collection PubMed
description The title compound, C(25)H(29)Br(2)NO, is a tert-pentyl analog of 2,4-bis­(2-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Par­thiban et al. (2008 ▶). Acta Cryst. E64, o2385]. Similar to its analog, the title compound exists in a twin-chair conformation with an equatorial orientation of the 2-bromo­phenyl groups. The benzene rings are inclined to each other at a dihedral angle of 29.6 (3)°. The tert-pentyl group on the cyclo­hexa­none ring also adopts an exocyclic equatorial disposition.
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spelling pubmed-34703182012-11-02 2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one Park, Dong Ho Ramkumar, V. Parthiban, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(29)Br(2)NO, is a tert-pentyl analog of 2,4-bis­(2-bromo­phen­yl)-3-aza­bicyclo­[3.3.1]nonan-9-one [Par­thiban et al. (2008 ▶). Acta Cryst. E64, o2385]. Similar to its analog, the title compound exists in a twin-chair conformation with an equatorial orientation of the 2-bromo­phenyl groups. The benzene rings are inclined to each other at a dihedral angle of 29.6 (3)°. The tert-pentyl group on the cyclo­hexa­none ring also adopts an exocyclic equatorial disposition. International Union of Crystallography 2012-09-19 /pmc/articles/PMC3470318/ /pubmed/23125731 http://dx.doi.org/10.1107/S1600536812039128 Text en © Park et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Park, Dong Ho
Ramkumar, V.
Parthiban, P.
2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title 2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full 2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_fullStr 2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_full_unstemmed 2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_short 2,4-Bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one
title_sort 2,4-bis(2-bromo­phen­yl)-7-tert-pentyl-3-aza­bicyclo­[3.3.1]nonan-9-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470318/
https://www.ncbi.nlm.nih.gov/pubmed/23125731
http://dx.doi.org/10.1107/S1600536812039128
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