Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate

In the title compound, C(22)H(24)O(14), the relative stereochemistry at the cyclo­butane ring is cis-anti-cis and the methyl groups in the bicyclic rings are syn to each other. The two carboxyl­ate groups attached to the same —C=C— bond are disordered over two sets of sites in a 0.603 (2):0.397 (2)...

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Detalles Bibliográficos
Autores principales: Lough, Alan J., Jack, Kelsey, Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470330/
https://www.ncbi.nlm.nih.gov/pubmed/23125743
http://dx.doi.org/10.1107/S1600536812039219
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author Lough, Alan J.
Jack, Kelsey
Tam, William
author_facet Lough, Alan J.
Jack, Kelsey
Tam, William
author_sort Lough, Alan J.
collection PubMed
description In the title compound, C(22)H(24)O(14), the relative stereochemistry at the cyclo­butane ring is cis-anti-cis and the methyl groups in the bicyclic rings are syn to each other. The two carboxyl­ate groups attached to the same —C=C— bond are disordered over two sets of sites in a 0.603 (2):0.397 (2) ratio. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into C(12) chains along [001] incorporating R (2) (2) (2)(10) rings.
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spelling pubmed-34703302012-11-02 Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate Lough, Alan J. Jack, Kelsey Tam, William Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(24)O(14), the relative stereochemistry at the cyclo­butane ring is cis-anti-cis and the methyl groups in the bicyclic rings are syn to each other. The two carboxyl­ate groups attached to the same —C=C— bond are disordered over two sets of sites in a 0.603 (2):0.397 (2) ratio. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into C(12) chains along [001] incorporating R (2) (2) (2)(10) rings. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470330/ /pubmed/23125743 http://dx.doi.org/10.1107/S1600536812039219 Text en © Lough et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lough, Alan J.
Jack, Kelsey
Tam, William
Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_full Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_fullStr Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_full_unstemmed Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_short Tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_sort tetra­methyl 1,4-dimethyl-13,14-dioxa­penta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470330/
https://www.ncbi.nlm.nih.gov/pubmed/23125743
http://dx.doi.org/10.1107/S1600536812039219
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AT tamwilliam tetramethyl14dimethyl1314dioxapentacyclo821147029038tetradeca511diene561112tetracarboxylate

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