Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate

The stereochemistry of the title compound, C(32)H(44)O(10), at the cyclo­butane ring is cis-anti-cis. The mol­ecule lies across an inversion center. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [100], forming R (2) (2)(6) rings.

Detalles Bibliográficos
Autores principales: Lough, Alan J., Jack, Kelsey, Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470331/
https://www.ncbi.nlm.nih.gov/pubmed/23125744
http://dx.doi.org/10.1107/S1600536812039220
_version_ 1782246251972001792
author Lough, Alan J.
Jack, Kelsey
Tam, William
author_facet Lough, Alan J.
Jack, Kelsey
Tam, William
author_sort Lough, Alan J.
collection PubMed
description The stereochemistry of the title compound, C(32)H(44)O(10), at the cyclo­butane ring is cis-anti-cis. The mol­ecule lies across an inversion center. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [100], forming R (2) (2)(6) rings.
format Online
Article
Text
id pubmed-3470331
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34703312012-11-02 Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate Lough, Alan J. Jack, Kelsey Tam, William Acta Crystallogr Sect E Struct Rep Online Organic Papers The stereochemistry of the title compound, C(32)H(44)O(10), at the cyclo­butane ring is cis-anti-cis. The mol­ecule lies across an inversion center. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [100], forming R (2) (2)(6) rings. International Union of Crystallography 2012-09-22 /pmc/articles/PMC3470331/ /pubmed/23125744 http://dx.doi.org/10.1107/S1600536812039220 Text en © Lough et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lough, Alan J.
Jack, Kelsey
Tam, William
Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_full Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_fullStr Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_full_unstemmed Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_short Tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
title_sort tetra-tert-butyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-5,6,11,12-tetra­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470331/
https://www.ncbi.nlm.nih.gov/pubmed/23125744
http://dx.doi.org/10.1107/S1600536812039220
work_keys_str_mv AT loughalanj tetratertbutyl1314dioxapentacyclo821147029038tetradeca511diene561112tetracarboxylate
AT jackkelsey tetratertbutyl1314dioxapentacyclo821147029038tetradeca511diene561112tetracarboxylate
AT tamwilliam tetratertbutyl1314dioxapentacyclo821147029038tetradeca511diene561112tetracarboxylate

Ejemplares similares