Hexamethyl 13,14-dioxapenta­cyclo­[8.2.1.1(4,7).0(2,9).0(3,8)]tetra­deca-5,11-diene-1,4,5,6,11,12-hexa­carboxyl­ate

In the title compound, C(24)H(24)O(14), the stereochemistry at the cyclo­butane ring is cis-anti-cis and the –COOMe groups in the bicyclic rings are syn to each other. The mol­ecule lies on a twofold rotation axis. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [001],...

Descripción completa

Detalles Bibliográficos
Autores principales: Lough, Alan J., Jack, Kelsey, Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3470332/
https://www.ncbi.nlm.nih.gov/pubmed/23125745
http://dx.doi.org/10.1107/S1600536812039232
Descripción
Sumario:In the title compound, C(24)H(24)O(14), the stereochemistry at the cyclo­butane ring is cis-anti-cis and the –COOMe groups in the bicyclic rings are syn to each other. The mol­ecule lies on a twofold rotation axis. In the crystal, weak C—H⋯O hydrogen bonds connect mol­ecules into chains along [001], forming R (2) (2)(10) rings.

Ejemplares similares